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In complexes off wea field ligands, Delt...

In complexes off wea field ligands, `Delta_(o) lt P` (pairing energy), the energy difference between `t_(2g) and e_(g)` sets is relatively less. Under the unfluence of strong field ligands, `Delta_(O) gt p` (Pairing energy), the energy difference between `t_(2g) and e_(g)` sets is relatively high.
Q. Select the correct increasing order of 10 Dq. value of chromium complexes:
(1) `[Cr(en)_(3)]^(3+)`
(2) `[Cr(o x)_(3)]^(3-)` ltBrgt (3) `[CrF_(6)]^(3-)`
(4) `[Cr(H_(2)O)_(6)]^(3+)`

A

`4 lt 3 lt 1 lt 2`

B

`3 lt 4 lt 2 lt 1`

C

`4 lt 3 lt 2 lt 1`

D

`3 lt 4 lt 1 lt 2`

Text Solution

Verified by Experts

The correct Answer is:
B
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VK JAISWAL-CO-ORDINATION COMPOUNDS-LEVEL 3 (PASSAGE TYPE)
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  2. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  3. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  4. In complexes off wea field ligands, Delta(o) lt P (pairing energy), th...

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  5. Complex compounds are molecular compounds which retain their identitie...

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  6. Complex compounds are molecular compounds which retain their identitie...

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  7. Complex compounds are molecular compounds which retain their identitie...

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  8. Recent X-ray work, IR and other spectroscopic methods have proved that...

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  9. Recent X-ray work, IR and other spectroscopic methods have proved that...

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  10. On the basic of stability of complex ion in the solution, complexes ma...

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  11. On the basic of stability of complex ion in the solution, complexes ma...

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  12. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  13. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  14. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  15. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  16. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  17. When degenerate d-orbitals of an isolated atom/ion come under influenc...

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  18. Magnetic moment, ionic conductance and colligative properties are usef...

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  19. Magnetic moment, ionic conductance and colligative properties are usef...

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  20. Magnetic moment, ionic conductance and colligative properties are usef...

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