Home
Class 12
CHEMISTRY
When degenerate d-orbitals of an isolate...

When degenerate d-orbitals of an isolated atom/ion come under influence of magnetic field of ligands, the degeneray is lost. The two set `t_(2g)(d_(xy),d_(yz),d_(xz)) and e_(g) (d_(x^(2))-d_(x^(2)-y^(2))` are either stabilized or destabilized depending upon the nature of magnetic field. it can be expressed diagrammatically as:

Value of CFSE depends upon nature of ligand and a spectrochemical series has been made experimentally, for tetrahedral complexes, `Delta` is about 4/9 times to `Delta_(0)` (CFSE for octahedral complex). this energy lies in visible region and i.e., why electronic transition are responsible for colour. such transition are not possible with `d^(0) and d^(10)` configuration.
Q. The d-orbitals, which are stabillized in an octahedral magnetic field, are:

A

`d_(xy) and d_(x^(2))`

B

`d_(x^(2)-y^(2)) and d_(x^(2))`

C

`d_(xy),d_(xz) and d_(yz)`

D

`d_(x^(2))` only

Text Solution

Verified by Experts

The correct Answer is:
C
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise ASSERTION-REASON TYPE QUESTIONS|26 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL|Exercise LEVEL 1|202 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL|Exercise Level 3 (Passive 11)|6 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL|Exercise SUBJECTIVE PROBLEMS|6 Videos
VK JAISWAL-CO-ORDINATION COMPOUNDS-LEVEL 3 (PASSAGE TYPE)
  1. On the basic of stability of complex ion in the solution, complexes ma...

    Text Solution

    |

  2. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  3. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  4. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  5. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  6. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  7. When degenerate d-orbitals of an isolated atom/ion come under influenc...

    Text Solution

    |

  8. Magnetic moment, ionic conductance and colligative properties are usef...

    Text Solution

    |

  9. Magnetic moment, ionic conductance and colligative properties are usef...

    Text Solution

    |

  10. Magnetic moment, ionic conductance and colligative properties are usef...

    Text Solution

    |

  11. The crystal field theory assumes interaction between metal ion and the...

    Text Solution

    |

  12. The crystal field theory assumes interaction between metal ion and the...

    Text Solution

    |

  13. The crystal field theory assumes interaction between metal ion and the...

    Text Solution

    |

  14. The magnetic property, dipole moment, plane of symmetry, colour and ab...

    Text Solution

    |

  15. The magnetic property, dipole moment, plane of symmetry, colour and ab...

    Text Solution

    |

  16. The magnetic property, dipole moment, plane of symmetry, colour and ab...

    Text Solution

    |

  17. Ligands are broadly classified into two classes classical and non-clas...

    Text Solution

    |

  18. Ligands are broadly classified into two classes classical and non-clas...

    Text Solution

    |

  19. Ligands are broadly classified into two classes classical and non-clas...

    Text Solution

    |

  20. An isomerr of the complex CoBrCl(2)(en)(2)(H(2)O), on reaction with co...

    Text Solution

    |