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Which of the following is a hypovalent m...

Which of the following is a hypovalent molecule species?

A

`NaF`

B

`COCl_(2)`

C

`NF_(4)^(+)`

D

`BeCl_(2)`

Text Solution

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The correct Answer is:
To determine which of the following is a hypovalent molecule species, we need to analyze each option based on the number of valence electrons around the central atom after bonding. A hypovalent species is defined as one that has fewer than 8 electrons in its valence shell. ### Step-by-Step Solution: 1. **Understanding Hypovalent Species:** - A hypovalent species is one that has less than 8 electrons in its valence shell after bonding. 2. **Analyzing Each Option:** - **Option A: NaF** - Sodium (Na) has 1 valence electron and fluorine (F) has 7 valence electrons. - When Na donates its electron to F, Na becomes Na⁺ and F becomes F⁻. - The resulting ion pair (Na⁺ and F⁻) does not form a molecule with a central atom that has fewer than 8 electrons. - Thus, NaF is not hypovalent. - **Option B: COCl₂** - Carbon (C) has 4 valence electrons, and it forms two bonds with two chlorine atoms (Cl), each contributing 1 electron. - The total number of electrons around carbon after bonding is 4 (from C) + 2 (from Cl) = 8. - Therefore, COCl₂ is not hypovalent. - **Option C: NF₄⁺** - Nitrogen (N) has 5 valence electrons. The positive charge indicates that one electron is removed. - Nitrogen forms four bonds with fluorine atoms, contributing 4 electrons. - The total number of electrons around nitrogen is 4 (from N) + 4 (from F) = 8. - Hence, NF₄⁺ is not hypovalent. - **Option D: BeCl₂** - Beryllium (Be) has 2 valence electrons and forms two bonds with two chlorine atoms. - Each bond contributes 2 electrons (1 from Be and 1 from Cl). - The total number of electrons around beryllium after bonding is 2 (from Be) + 2 (from Cl) = 4. - Since 4 is less than 8, BeCl₂ is hypovalent. 3. **Conclusion:** - The hypovalent species among the given options is **D: BeCl₂**.

To determine which of the following is a hypovalent molecule species, we need to analyze each option based on the number of valence electrons around the central atom after bonding. A hypovalent species is defined as one that has fewer than 8 electrons in its valence shell. ### Step-by-Step Solution: 1. **Understanding Hypovalent Species:** - A hypovalent species is one that has less than 8 electrons in its valence shell after bonding. 2. **Analyzing Each Option:** ...
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