Variation of equilibrium constan K with temperature is given by van't Hoff equation `InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT)` for this equation, `(Delta_(r)H^(@))` can be evaluated if equilibrium constans `K_(1)` and `K_(2)` at two temperature `T_(1)` and `T_(2)` are known. `log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)]` For an isomerization `X(g)hArrY(g)` the temperature dependency of equilibrium cohnstant is given by : `lnK=2-(1000)/T` The value of `Delta_(r)S^(@)` at `300 K` is :
A
`2` R
B
`2/R`
C
`1000` R
D
None of these
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Variation of equilibrium constan K with temperature is given by van't Hoff equation InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT) for this equation, (Delta_(r)H^(@)) can be evaluated if equilibrium constans K_(1) and K_(2) at two temperature T_(1) and T_(2) are known. log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)] Select the correct statement :
Variation of K with temperature as given by van't Hoff equation can be written as
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The effect of temperature on equilibrium constant is expressed as (T_(2)gtT_(1)) log K_(2)//K_(1)=(-DeltaH)/(2.303)[(1)/(T_(2))-(1)/(T_(1))] . For endothermic, false statement is
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