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How can CH3D be prepared from CH4 ?...

How can `CH_3D` be prepared from `CH_4` ?

Text Solution

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`CH_4overset(Br_2)underset(hnu,Delta)toCH_3Broverset(Mg)underset("Dry ether")toCH_3MgBroverset(D_2O)toCH_3D+Mg(OD)Br`
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Knowledge Check

  • CH_3 Br can be prepared by

    A
    `CH_3COOAg+Br_2 oversetDeltararr`
    B
    `CH_4+NBS rarr`
    C
    `CH_3COOHoverset(SOCl_2)rarr`
    D
    Both (1) & (2) are correct

  • Benzyl chloride (C_6H_5CH_2Cl) can be prepared from toluene by chlorination with

    A
    `SO_2Cl_2`
    B
    `SOCl_2`
    C
    `Cl_2//hv`
    D
    NaOCl

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    How CH_(3)MgI could be used to prepare methoxy ethane? (write arrowhead equation only)

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