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How can CH3D be prepared from CH4 ?...

How can `CH_3D` be prepared from `CH_4` ?

Text Solution

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`CH_4overset(Br_2)underset(hnu,Delta)toCH_3Broverset(Mg)underset("Dry ether")toCH_3MgBroverset(D_2O)toCH_3D+Mg(OD)Br`
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Knowledge Check

  • CH_3 Br can be prepared by

    A
    `CH_3COOAg+Br_2 oversetDeltararr`
    B
    `CH_4+NBS rarr`
    C
    `CH_3COOHoverset(SOCl_2)rarr`
    D
    Both (1) & (2) are correct

  • Benzyl chloride (C_6H_5CH_2Cl) can be prepared from toluene by chlorination with

    A
    `SO_2Cl_2`
    B
    `SOCl_2`
    C
    `Cl_2//hv`
    D
    NaOCl
    • CHHAYA PUBLICATION-HYDROCARBONS-(QUESTION-ANSWER ZONE FOR BOARD EXAMINATION (Short answer type)
    1. How can CH3D be prepared from CH4 ?

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    2. The preparation of which of the following alkanes by Wurtz reaction ...

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    3. The preparation of which of the following alkanes by Wurtz reaction ...

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    4. The preparation of which of the following alkanes by Wurtz reaction ...

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    5. When a concentrated aqueous solution of a mixture of sodium salts of t...

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    6. Boiling points of three isomeric pentanes are 36.2^@C ,28^@C and 9.5^@...

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    7. Why are the alkanes chemically inert ?

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    8. How can an alkane having one carbon atom less be prepared from a carbo...

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    9. Write the structure and the name of the monobromoderivative which is o...

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    10. Write the structures and names of the principal products, A and B obta...

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    11. Possible methods for preparation of 4-methyl-2-pentyne are given. Whic...

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    12. Arrange the following compounds in the increasing order of their acidi...

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    13. Arrange the following compounds in the increasing order of their acidi...

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    14. An alkane (molecular mass 72) produces only one monochloro derivative....

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    15. Three separate cylinders contain methane, ethylene & acetylene respe...

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    16. Give example of an alkene which on oxidation by acidic solution of KM...

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    17. C2H2overset(Hg^(2+))underset(dil.H2SO4)toAoverset(H2)underset(Ni)toBov...

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    18. Acetylene does not react with NaOH or KOH even though it possesses aci...

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    19. Write the products obtained when propynide ion (CH3C-=overset(Theta)C"...

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    20. Write the products obtained when propynide ion (CH3C-=overset(Theta)C"...

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