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Which one of the following ions exhibits...

Which one of the following ions exhibits d - d transition and paramagnetism as well -

A

`MnO_(4)^(2-)`

B

`CrO_(4)^(2-)`

C

`MnO_(4)^(-)`

D

`Cr_(2)O_(7)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
A

`MnO_(4)^(2-)rarr Mn^(6+):[Ar]3d^(1)`
Only `MnO_(4)^(2-)` has one d - electron. Thus it can undergo d - d transition.
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CHHAYA PUBLICATION-D - AND F - BLOCK ELEMENTS -ENTRANCE QUESTION BANK
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  3. Which one of the following ions exhibits d - d transition and paramagn...

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  4. Match the metal ions given in column - I with the spin magnetic moment...

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  5. MnO(3) in an acidic medium dissociates into -

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  6. Which is not stable under ambient condition -

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  7. Magnetic moment of Cr^(2+) is nearest to -

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  8. Which of the following does not exist -

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  9. Which of the following is most basic -

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  10. When calomel is treated with ammonium hydroxide, a black substance is ...

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  11. Maximum number of unpaired electrons are present in -

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  12. Which of the following elements has lowest melting point -

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  13. In acidic medium, KMnO(4) converts H(2)S into -

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  14. Choose the correctly paired gaseous cation and its magnetic (spin only...

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  15. KMnO(4) in alkaline medium changes to -

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  16. Colour imparted by Co(II) compounds to glass is -

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  17. Copper sulphate is dissolved in water containing for making Bordeaus ...

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  18. Among the following, the compound that is both paramagnetic and colour...

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  19. The colourless species is -

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  20. Least number of oxidation states is shown by -

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