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Consider the following reactions: (i) ...

Consider the following reactions:
(i) `H^(+)(aq)+OH^(-)(aq)rarrH_(2)O(l)` ,
`DeltaH==-X_(1)Kjmol^(-1)`
(ii) `H_(2)(g)+(1)/(2)O_(2)(g)rarrH_(2)O(l),DeltaH=-X_(2)Kjmol^(-1)`
(iii) `CO_(2)(g)+H_(2)(g)rarrCO(g)+H_(2)O(l)` ,
`DeltaH=-X_(3)KJmol^(-1)`
(iv) `C_(2)H_(2)(g)+(5)/(2)O_(2)(g)rarr2CO_(2)(g)+H_(2)O(l)` ,
`DeltaH=+X_(4)KJmol^(-1)`
Enthanlpy of formation of `H_(2)O(l)` is

A

`+X_3kJmol^(-1)`

B

`-X_4kJmol^(-1)`

C

`+X_1kJmol^(-1)`

D

`-X_2kJmol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
D
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Consider the following reaction :- (a) H_(aq)^(+)+CI_(aq)^(-)toHCI_(l),DeltaH=-X_(1) KJmol^(-1) (b) H_2(g)^(+)+CI_2(g)to2HCI_(l),DeltaH=-X_(2) KJmol^(-1) ( c) (1)/(2)H_(2(g))+(1)/(2)CI_(2(g))toHCI_(l),DeltaH=-X_(3) KJmol^(-1) (d) H_((g))+CI_((g))toHCI_(l),DeltaH=-X_(4) KJmol^(-1) Enthalpy of formation of HCI_(l) is :-

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