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According of Langmuir adsorption isother...

According of Langmuir adsorption isotherm amount of gas adsorbed at very low pressure

A

Directly propoftional to the pressure

B

Proportional to `P^(1//n)` (where ` n gt 1` )

C

Inverself proportional to the pressure

D

Independent to the pressure of the gas

Text Solution

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding Adsorption**: - Adsorption is the process where particles (solid, liquid, or gas) accumulate on the surface of a solid. The particles that accumulate are called adsorbates, while the solid surface is called the adsorbent. 2. **Langmuir Adsorption Isotherm**: - The Langmuir adsorption isotherm describes how the amount of gas adsorbed on a solid surface varies with pressure at a constant temperature. The mathematical expression for the Langmuir isotherm is given by: \[ \frac{x}{m} = \frac{aP}{1 + bP} \] where: - \( x \) = mass of the adsorbate (gas) - \( m \) = mass of the adsorbent (solid) - \( P \) = pressure of the gas - \( a \) and \( b \) are constants. 3. **Analyzing Very Low Pressure**: - At very low pressures, the term \( bP \) becomes negligible compared to 1. Therefore, we can simplify the equation: \[ 1 + bP \approx 1 \] - This leads to: \[ \frac{x}{m} = \frac{aP}{1} = aP \] 4. **Conclusion**: - From the simplified equation, we can see that at very low pressure, the amount of gas adsorbed (\( \frac{x}{m} \)) is directly proportional to the pressure (\( P \)). This means that as the pressure increases, the amount of gas adsorbed also increases linearly. ### Final Answer: According to the Langmuir adsorption isotherm, at very low pressure, the amount of gas adsorbed is directly proportional to the pressure. ---
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