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The acidic hydrolysis of ether (X) shown...

The acidic hydrolysis of ether (X) shown below is fastest when.

A

One phenyl group is replaced by a methyl group

B

One phenyl group is replaced by a para-methoxyphenyl group

C

Two phenyl groups a replaced by two paramethoxyphenyl groups

D

No structure change is made to X

Text Solution

Verified by Experts

The correct Answer is:
C

`Ph_(3)C-OR underset(H_(2)O)overset(H^(o+))to Ph_(3)C-OH+ROH`
The reaction proceeds by `S_(N^(1))` Mechanism

Greater the electron releasing effect of the attached groups greater is the stability of intermediate carbocation , and faster is the rate of reaction.
If two pj- groups are replaced by MeO
groups , strong +M effect of MeO-groups stabilize, the carbocation better there by making the reaction faster.
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