The substrate will be binded to the active site of the enzyme through
a) Ionic binding
b) Hydogen bonding
c) van der Waals interactions
d) Dipole-dipole interactions
Correct answer is
The substrate will be binded to the active site of the enzyme through
a) Ionic binding
b) Hydogen bonding
c) van der Waals interactions
d) Dipole-dipole interactions
Correct answer is
a) Ionic binding
b) Hydogen bonding
c) van der Waals interactions
d) Dipole-dipole interactions
Correct answer is
A
a, b and c only
B
b, c and d only
C
a, b and d only
D
a, b, c and d
Text Solution
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The correct Answer is:
D
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Physicists firmly believe that all forces operating in nature are, in fact, different aspects of a single force, the so called “super-force' and it is in this context that : a) Newton united terrestrial gravitation (TG) and astronomical gravitation (AG) into single Gravitational Interaction (GI) b) Hans Oersted and Michael Faraday demonstrated that electric interaction (EI) and magnetic interactions (MI) wre interlinked. Subsequently, these interactions were unified into a single interaction, called Electromagnetic Interaction (EMI) by Clerk Maxwell. c) In 1920, Einstein tried to prove that gravitational interaction and electromagnetic interactions were the same, but he never succeeded. Where Einstein and other great scientists of the last century failed, their successors successfully combined weak interaction (WI) with electromagnetic interaction (EI) into a single Electro Weak Interaction (EWI). d) Grand Unification Theories (GUIS) are being actively pursued to unify strong interaction (SI) with electro weak interaction into so called Grand Unified Interaction (GUI). e) And finally, theories of Everything (TOE) are attempting to unify gravitational interaction with GUI into that elusive superforce, called Universal Interaction (UI). The various interactions operating in nature have been represented in figure Here, straight arrows represent what has been accomplished so far and the dotted arrows represent what is being pursued towards the unification of these interactions. The grand unification theory as diagram is hopefully a combination of
(A) Competitive inhibitors compete with natural substrate for their attachment on the active sites of enzymes. (R) In competitive inhibition, inhibitor binds to the allosteric site of the enzyme.
Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 A diatomic molecule has a dipole moment of 1.2 D. If the bond length is 1.0 xx 10^(-8) cm, what fraction of charge does exist on each atom?
Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 Arrange the following compounds in increasing order of dipole moments, toluene (I), o- dichlorobenzene (II), m-dicblorobenzene (III) and p dichlorobenzene (IV) :
Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 The dipole moment of NF_(3) is very much less than that of NH_(3) because :
Covalent molecules formed by heteroatoms bound to have some ionic character. The ionic character is due to shifting of the electron pair towards A or B in the molecule AB. Hence, atoms acquire small and equal charge but opposite in sign. Such a bond which has some ionic character is described as polar covalent bond. Polar covalent molecules can exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length, d for the bond. The unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of molecules depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moments help to predict the geometry of the molecules. Dipole moment values can be used to distinguish between cis-and traps-isomers, ortho-, meta-and para-forms of a substance, etc. The percentage of ionic character of a bond can be calculated by the application of the following formula : % " ionic character " = ("Experimental value of dipole moment ")/("Theoretical value of dipole moment ") xx 100 Which are non-polar molecules?
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