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In which of the following compounds, an ...

In which of the following compounds, an elements exhibits two different oxidation states?

A

`NH_(2)OH`

B

`NH_(4)NO_(3)`

C

`N_(2)H_(4)`

D

`N_(3)H`

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which of the given compounds an element exhibits two different oxidation states, we will analyze each compound step by step. ### Step 1: Analyze NH2OH (Hydroxylamine) 1. The compound is NH2OH. 2. The hydroxyl group (OH) has an oxidation state of -1. 3. Let the oxidation state of nitrogen (N) be \( x \). 4. The total oxidation state can be set up as: \[ x + 2(+1) + (-1) = +1 \] Simplifying this gives: \[ x + 2 - 1 = +1 \implies x + 1 = +1 \implies x = 0 \] 5. Therefore, in NH2OH, nitrogen has an oxidation state of 0. ### Step 2: Analyze NH4NO3 (Ammonium Nitrate) 1. The compound is NH4NO3. 2. This can be split into two parts: NH4+ (ammonium) and NO3- (nitrate). 3. For NH4+, let the oxidation state of nitrogen be \( x \): \[ x + 4(+1) = +1 \implies x + 4 = +1 \implies x = -3 \] 4. For NO3-, let the oxidation state of nitrogen be \( y \): \[ y + 3(-2) = -1 \implies y - 6 = -1 \implies y = +5 \] 5. Thus, nitrogen in NH4NO3 exhibits two oxidation states: -3 in NH4+ and +5 in NO3-. ### Step 3: Analyze N2H4 (Hydrazine) 1. The compound is N2H4. 2. Let the oxidation state of nitrogen be \( x \): \[ 2x + 4(+1) = 0 \implies 2x + 4 = 0 \implies 2x = -4 \implies x = -2 \] 3. Therefore, nitrogen in N2H4 has an oxidation state of -2. ### Step 4: Analyze N3H (Hydrazoic Acid) 1. The compound is N3H. 2. Let the oxidation state of nitrogen be \( z \): \[ 3z + 1(+1) = 0 \implies 3z + 1 = 0 \implies 3z = -1 \implies z = -\frac{1}{3} \] 3. Therefore, nitrogen in N3H has an oxidation state of -1/3. ### Conclusion From our analysis: - **NH2OH**: Nitrogen = 0 - **NH4NO3**: Nitrogen = -3 (in NH4+) and +5 (in NO3-) - **N2H4**: Nitrogen = -2 - **N3H**: Nitrogen = -1/3 The only compound where an element exhibits two different oxidation states is **NH4NO3**. ### Final Answer **The compound in which an element exhibits two different oxidation states is NH4NO3.** ---

To determine in which of the given compounds an element exhibits two different oxidation states, we will analyze each compound step by step. ### Step 1: Analyze NH2OH (Hydroxylamine) 1. The compound is NH2OH. 2. The hydroxyl group (OH) has an oxidation state of -1. 3. Let the oxidation state of nitrogen (N) be \( x \). 4. The total oxidation state can be set up as: \[ ...
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