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The number of geometrical isomers for [P...

The number of geometrical isomers for `[Pt(NH_(3))_(2)CI_(2)]` is

A

3

B

4

C

1

D

2

Text Solution

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The correct Answer is:
To determine the number of geometrical isomers for the coordination compound \([Pt(NH_3)_2Cl_2]\), we can follow these steps: ### Step 1: Identify the Coordination Number and Geometry The coordination number of platinum in this complex is 4, as it is bonded to two ammonia (\(NH_3\)) ligands and two chloride (\(Cl\)) ligands. The geometry of a coordination compound with a coordination number of 4 can be either tetrahedral or square planar. For platinum(II) complexes, the geometry is typically square planar. **Hint:** Remember that the geometry of a coordination complex can influence the types of isomers that can form. ### Step 2: Determine Possible Isomers In square planar complexes, geometrical isomers arise from the arrangement of the ligands around the central metal atom. The two types of geometrical isomers are: - **Cis Isomer:** The similar ligands are adjacent to each other. - **Trans Isomer:** The similar ligands are opposite each other. For \([Pt(NH_3)_2Cl_2]\): - **Cis Isomer:** Both \(Cl\) ligands are adjacent to each other, and both \(NH_3\) ligands are adjacent to each other. - **Trans Isomer:** One \(Cl\) ligand is opposite the other \(Cl\) ligand, and one \(NH_3\) ligand is opposite the other \(NH_3\) ligand. **Hint:** Visualizing the arrangement of ligands can help you identify the types of isomers. ### Step 3: Count the Geometrical Isomers From the arrangements discussed: - We have identified one cis isomer and one trans isomer. Thus, the total number of geometrical isomers for \([Pt(NH_3)_2Cl_2]\) is **2** (one cis and one trans). **Hint:** When counting isomers, ensure that you consider all possible arrangements of the ligands. ### Conclusion The number of geometrical isomers for the compound \([Pt(NH_3)_2Cl_2]\) is **2**. **Final Answer:** 2

To determine the number of geometrical isomers for the coordination compound \([Pt(NH_3)_2Cl_2]\), we can follow these steps: ### Step 1: Identify the Coordination Number and Geometry The coordination number of platinum in this complex is 4, as it is bonded to two ammonia (\(NH_3\)) ligands and two chloride (\(Cl\)) ligands. The geometry of a coordination compound with a coordination number of 4 can be either tetrahedral or square planar. For platinum(II) complexes, the geometry is typically square planar. **Hint:** Remember that the geometry of a coordination complex can influence the types of isomers that can form. ### Step 2: Determine Possible Isomers ...
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