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Two ideal monoatomic and diatomic gases ...

Two ideal monoatomic and diatomic gases are mixed with one another to form an ideal gas mixture. The equation of the adiabatic process of the mixture is `PV^(gamma)=` constant, where `gamma=(11)/(7)` If `n_(1)` and `n_(2)` are the number of moles of the monoatomic and diatomic gases in the mixture respectively, find the ratio `(n_(1))/(n_(2))`

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To solve the problem of finding the ratio of the number of moles of monoatomic gas \( n_1 \) to diatomic gas \( n_2 \) in an ideal gas mixture undergoing an adiabatic process, we follow these steps: ### Step 1: Understand the given information We know that the adiabatic process for the mixture is described by the equation: \[ PV^\gamma = \text{constant} \] where \( \gamma = \frac{11}{7} \). ### Step 2: Recall the definition of \( \gamma \) For an ideal gas, \( \gamma \) is defined as: \[ \gamma = \frac{C_p}{C_v} \] where \( C_p \) is the specific heat at constant pressure and \( C_v \) is the specific heat at constant volume. ### Step 3: Determine \( C_p \) and \( C_v \) for monoatomic and diatomic gases For a monoatomic gas: - \( C_v = \frac{3}{2} R \) - \( C_p = \frac{5}{2} R \) For a diatomic gas: - \( C_v = \frac{5}{2} R \) - \( C_p = \frac{7}{2} R \) ### Step 4: Write the expressions for \( C_p \) and \( C_v \) of the mixture The specific heats for the mixture can be expressed as: \[ C_{p,\text{mixture}} = \frac{n_1 C_{p1} + n_2 C_{p2}}{n_1 + n_2} \] \[ C_{v,\text{mixture}} = \frac{n_1 C_{v1} + n_2 C_{v2}}{n_1 + n_2} \] ### Step 5: Substitute the values of \( C_p \) and \( C_v \) Substituting the values into the equations: \[ C_{p,\text{mixture}} = \frac{n_1 \left(\frac{5}{2} R\right) + n_2 \left(\frac{7}{2} R\right)}{n_1 + n_2} \] \[ C_{v,\text{mixture}} = \frac{n_1 \left(\frac{3}{2} R\right) + n_2 \left(\frac{5}{2} R\right)}{n_1 + n_2} \] ### Step 6: Write the expression for \( \gamma \) of the mixture Now, substituting these into the expression for \( \gamma \): \[ \gamma = \frac{C_{p,\text{mixture}}}{C_{v,\text{mixture}}} = \frac{\frac{n_1 \left(\frac{5}{2} R\right) + n_2 \left(\frac{7}{2} R\right)}{n_1 + n_2}}{\frac{n_1 \left(\frac{3}{2} R\right) + n_2 \left(\frac{5}{2} R\right)}{n_1 + n_2}} \] ### Step 7: Simplify the expression This simplifies to: \[ \gamma = \frac{n_1 \left(\frac{5}{2}\right) + n_2 \left(\frac{7}{2}\right)}{n_1 \left(\frac{3}{2}\right) + n_2 \left(\frac{5}{2}\right)} \] ### Step 8: Substitute the value of \( \gamma \) Substituting \( \gamma = \frac{11}{7} \): \[ \frac{n_1 \left(\frac{5}{2}\right) + n_2 \left(\frac{7}{2}\right)}{n_1 \left(\frac{3}{2}\right) + n_2 \left(\frac{5}{2}\right)} = \frac{11}{7} \] ### Step 9: Cross-multiply to eliminate the fraction Cross-multiplying gives: \[ 7\left(n_1 \left(\frac{5}{2}\right) + n_2 \left(\frac{7}{2}\right)\right) = 11\left(n_1 \left(\frac{3}{2}\right) + n_2 \left(\frac{5}{2}\right)\right) \] ### Step 10: Expand and simplify Expanding both sides: \[ \frac{35}{2} n_1 + \frac{49}{2} n_2 = \frac{33}{2} n_1 + \frac{55}{2} n_2 \] ### Step 11: Rearranging the equation Rearranging gives: \[ 35 n_1 + 49 n_2 = 33 n_1 + 55 n_2 \] \[ 2 n_1 = 6 n_2 \] ### Step 12: Solve for the ratio \( \frac{n_1}{n_2} \) Thus, we find: \[ \frac{n_1}{n_2} = \frac{6}{2} = 3 \] ### Final Answer The ratio of the number of moles of monoatomic gas to diatomic gas is: \[ \frac{n_1}{n_2} = 3 \]
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