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The reaction: ArN2Cl overset(Cu//HCl)ra...

The reaction: `ArN_2Cl overset(Cu//HCl)rarrArCl +N_2 + CuCl` is known as: -

A

Balz Schiemann reaction

B

Sandmeyers reaction

C

Finkelstein reaction

D

Gattermann reaction

Text Solution

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The correct Answer is:
To determine the name of the reaction given by the equation: \[ \text{ArN}_2\text{Cl} \xrightarrow{\text{Cu/HCl}} \text{ArCl} + \text{N}_2 + \text{CuCl} \] we can analyze the components and the process involved. ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: - The reactant is aryl diazonium chloride (ArN₂Cl). - The products are aryl chloride (ArCl), nitrogen gas (N₂), and copper(I) chloride (CuCl). 2. **Understand the Role of Copper and Hydrochloric Acid**: - In this reaction, copper acts as a reducing agent and hydrochloric acid provides the chloride ion necessary for the substitution reaction. 3. **Recognize the Type of Reaction**: - The reaction involves the substitution of the diazonium group (N₂) with a chlorine atom (Cl) from HCl, leading to the formation of aryl chloride. 4. **Relate to Known Reactions**: - This reaction is characteristic of the Sandmeyer reaction, which involves the conversion of aryl diazonium salts into aryl halides using copper(I) halides in the presence of a halogen acid. 5. **Conclusion**: - Therefore, the reaction given is known as the **Sandmeyer Reaction**. ### Final Answer: The reaction \( \text{ArN}_2\text{Cl} \xrightarrow{\text{Cu/HCl}} \text{ArCl} + \text{N}_2 + \text{CuCl} \) is known as the **Sandmeyer Reaction**. ---
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