Home
Class 12
CHEMISTRY
Assertion : Magnetic moment of Dy is the...

Assertion : Magnetic moment of Dy is the highest among langthanoids.
Reason : Orbital motion contributes magnetic moment.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reasonb is false

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question regarding the magnetic moment of Dysprosium (Dy) among lanthanides, we will analyze both the assertion and the reason step by step. ### Step 1: Understanding the Assertion The assertion states that "the magnetic moment of Dy is the highest among lanthanides." - Dysprosium (Dy) is a lanthanide element with atomic number 66. - In lanthanides, the magnetic moment is primarily due to the presence of unpaired electrons in the f-orbitals, specifically the 4f orbital. ### Step 2: Evaluating the Magnetic Moment The magnetic moment (μ) can be calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. - Dysprosium has 5 unpaired electrons in its 4f orbital configuration. - Therefore, substituting \( n = 5 \): \[ \mu = \sqrt{5(5 + 2)} = \sqrt{35} \] This indicates a relatively high magnetic moment compared to other lanthanides, confirming that Dy does indeed have one of the highest magnetic moments. ### Step 3: Understanding the Reason The reason states that "orbital motion contributes to the magnetic moment." - In lanthanides, the electrons in the 4f orbitals experience significant screening effects, which means that their orbital motion does contribute to the overall magnetic moment. - The contribution from orbital motion is significant, especially when considering the unpaired electrons. ### Step 4: Conclusion Both the assertion and the reason are correct. The assertion that Dy has the highest magnetic moment among lanthanides is supported by the reason that orbital motion contributes to the magnetic moment. ### Final Answer Both the assertion and the reason are true, and the reason correctly explains the assertion.

To solve the assertion and reason question regarding the magnetic moment of Dysprosium (Dy) among lanthanides, we will analyze both the assertion and the reason step by step. ### Step 1: Understanding the Assertion The assertion states that "the magnetic moment of Dy is the highest among lanthanides." - Dysprosium (Dy) is a lanthanide element with atomic number 66. - In lanthanides, the magnetic moment is primarily due to the presence of unpaired electrons in the f-orbitals, specifically the 4f orbital. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Magnetic moment of the lap

Unit of magnetic moment is

Magnetic moment of Cr^(2+) is nearest to

Magnetic moment of Fe is similar to that of

The magnetic moment of atomic neon is

Assertion : Magnetic moment of Mn^(2+) is less than Cr^(2+) Reason: Higher the atomic number smaller is the magnetic moment.

Unit of magnetic dipole moment is

Transition metals and many of their compounds show paramagnetic behaviour where there are unpaired electron or electrons. The magnetic moment arises from the spin and orbital motions in ions or molecule. Magnetic moment of n unpaired electrons is given as mu=sqrt(n(n+2)) Bohr magneton Magnetic moment increases as the number of unpaired electrons increases. Q. Which among the following ions has maximum value of magnetic moment

Assertion: Diamagnetism is universal, it is present in all materials Reason: Field due to induced magnetic moment is opposite to the magnetising field.

Transition metals and many of their compounds show paramagnetic behaviour where there are unpaired electron or electrons. The magnetic moment arises from the spin and orbital motions in ions or molecule. Magnetic moment of n unpaired electrons is given as mu=sqrt(n(n+2)) Bohr magneton Magnetic moment increases as the number of unpaired electrons increases. Q. In 3d series the maximum magnetic moment is shown by