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Assertion : Pb(2)O(4) react with HNO(2) ...

Assertion : `Pb_(2)O_(4)` react with `HNO_(2)` and form `PbO_(2)`
Reason: Lead is stable in +4 oxidation state.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that `Pb2O4` reacts with `HNO2` (nitrous acid) to form `PbO2` (lead dioxide). - We need to verify if this reaction occurs. 2. **Chemical Reaction**: - The chemical reaction can be represented as: \[ Pb_2O_4 + 4HNO_2 \rightarrow 2PbO_2 + 2H_2O + 2Pb(NO_3)_2 \] - This shows that `Pb2O4` does indeed react with `HNO2` to produce `PbO2`, confirming that the assertion is correct. 3. **Understanding the Reason**: - The reason states that lead is stable in the +4 oxidation state. - Lead (Pb) can exhibit oxidation states of +2 and +4. However, due to the inert pair effect, the +2 oxidation state is more stable for lead in many compounds. 4. **Evaluating the Reason**: - While lead can exist in the +4 state, it is not the most stable state. The +2 state is more stable due to the inert pair effect, which suggests that the outermost s-electrons are less available for bonding. - Therefore, the reason provided is incorrect. 5. **Conclusion**: - The assertion is true, but the reason is false. Thus, the correct answer is that the assertion is true and the reason is false. ### Final Answer: - Assertion: True - Reason: False

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that `Pb2O4` reacts with `HNO2` (nitrous acid) to form `PbO2` (lead dioxide). - We need to verify if this reaction occurs. ...
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