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The term which accounts for intermolecul...

The term which accounts for intermolecular force in van der Waal's equation is :

A

`(V-b)`

B

`(RT)^(-1)`

C

`(P+a//V^(2))`

D

`RT`

Text Solution

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The correct Answer is:
To solve the question regarding the term that accounts for intermolecular forces in van der Waals' equation, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Van der Waals Equation**: The van der Waals equation is given by: \[ \left( P + \frac{a n^2}{V^2} \right)(V - nb) = nRT \] Here, \( P \) is the pressure, \( V \) is the volume, \( n \) is the number of moles, \( R \) is the ideal gas constant, and \( T \) is the temperature. 2. **Identify the Terms**: In the equation, there are two correction terms: - The term \( \frac{a n^2}{V^2} \) accounts for the intermolecular forces of attraction. - The term \( nb \) accounts for the volume occupied by the gas particles themselves. 3. **Focus on Intermolecular Forces**: The term \( a \) in the equation represents the strength of the intermolecular forces. The larger the value of \( a \), the stronger the intermolecular forces between the gas molecules. 4. **Conclusion**: Therefore, the term that accounts for intermolecular forces in van der Waals' equation is \( \frac{a n^2}{V^2} \). ### Final Answer: The term which accounts for intermolecular force in van der Waals' equation is \( \frac{a n^2}{V^2} \). ---

To solve the question regarding the term that accounts for intermolecular forces in van der Waals' equation, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Van der Waals Equation**: The van der Waals equation is given by: \[ \left( P + \frac{a n^2}{V^2} \right)(V - nb) = nRT ...
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