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Conformations are different arrangements...

Conformations are different arrangements of atoms that are interconverted by rotation about single bond.
In eclipsed conformation, the C-H bond on-one carbon is directly aligned with C-H bond on the adjacent carbon.
In staggered conformation, the c H bond on one carbon biseçt, the H G H bond angle on adjacent carbon.
The angle that separates a bond on one atom from a bond on a adjacent atom is called a dihedral angle.
A staggered conformation with two larger groups `180^(@)` from each other is called anti. A staggered conformation with two larger group `60^(@)` from each other is called gauche.
Identify the most stable conformer of 2-fluoro, ethanol among the following:

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To identify the most stable conformer of 2-fluoroethanol, we need to analyze the conformations based on the definitions provided in the question and the characteristics of the molecule. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Structure of 2-Fluoroethanol 2-Fluoroethanol has the following structure: - Ethanol (C2H5OH) with a fluorine (F) atom attached to the second carbon. - The molecular formula is C2H5OF. ### Step 2: Identify Possible Conformations The two main types of conformations we need to consider are: - **Eclipsed Conformation**: where the C-H bonds on adjacent carbons are aligned. - **Staggered Conformation**: where the C-H bonds on adjacent carbons are staggered, minimizing steric hindrance. ### Step 3: Analyze the Staggered Conformation In the staggered conformation, we have two specific arrangements to consider: - **Anti Conformation**: where the larger groups (OH and F) are 180 degrees apart. - **Gauche Conformation**: where the larger groups are 60 degrees apart. ### Step 4: Evaluate Stability - **Eclipsed Conformation**: This is generally less stable due to increased steric strain between the overlapping electron clouds of the bonds. - **Staggered Conformation**: This is more stable due to minimized steric strain. ### Step 5: Check for Hydrogen Bonding In the case of 2-fluoroethanol: - The hydroxyl (OH) group can form hydrogen bonds with the fluorine (F) atom when they are in a staggered conformation. - This hydrogen bonding increases the stability of the conformation. ### Step 6: Determine the Most Stable Conformation - The **anti conformation** is typically the most stable due to the 180-degree separation of larger groups. - However, if the **gauche conformation** allows for hydrogen bonding between the OH and F groups, it may be more stable than the anti conformation. ### Conclusion After analyzing the conformations, the most stable conformer of 2-fluoroethanol is the **gauche conformation** where the OH and F groups can engage in hydrogen bonding. ### Final Answer The most stable conformer of 2-fluoroethanol is the **gauche conformation**. ---

To identify the most stable conformer of 2-fluoroethanol, we need to analyze the conformations based on the definitions provided in the question and the characteristics of the molecule. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Structure of 2-Fluoroethanol 2-Fluoroethanol has the following structure: - Ethanol (C2H5OH) with a fluorine (F) atom attached to the second carbon. - The molecular formula is C2H5OF. ### Step 2: Identify Possible Conformations ...
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