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Find the molar specific heat of the proc...

Find the molar specific heat of the process `p=a/T` for a monoatomic gas, a being constant.

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To find the molar specific heat of the process defined by \( P = \frac{a}{T} \) for a monoatomic gas, we can follow these steps: ### Step 1: Define Molar Specific Heat The molar specific heat \( C \) is defined as the amount of heat added per unit temperature change. Mathematically, it can be expressed as: \[ C = \frac{dQ}{dT} \] ### Step 2: Apply the First Law of Thermodynamics According to the first law of thermodynamics: \[ dU = dQ - dW \] This can be rearranged to express \( dQ \): \[ dQ = dU + dW \] ### Step 3: Express \( dU \) for a Monoatomic Gas For a monoatomic ideal gas, the change in internal energy \( dU \) is given by: \[ dU = nC_V dT \] For one mole of gas (\( n = 1 \)), this simplifies to: \[ dU = C_V dT \] ### Step 4: Express \( dW \) The work done \( dW \) in a process can be expressed as: \[ dW = P dV \] ### Step 5: Substitute \( dQ \) in Terms of \( dT \) Substituting the expressions for \( dU \) and \( dW \) into the equation for \( dQ \): \[ dQ = C_V dT + P dV \] ### Step 6: Differentiate with Respect to \( T \) Now, we differentiate \( dQ \) with respect to \( T \): \[ \frac{dQ}{dT} = C_V + P \frac{dV}{dT} \] Thus, we have: \[ C = C_V + P \frac{dV}{dT} \] ### Step 7: Relate \( P \) and \( V \) Using the Ideal Gas Law Using the ideal gas law \( PV = nRT \), for one mole (\( n = 1 \)): \[ P = \frac{RT}{V} \] Given \( P = \frac{a}{T} \), we can set these equal: \[ \frac{RT}{V} = \frac{a}{T} \] From this, we can solve for \( V \): \[ V = \frac{RT^2}{a} \] ### Step 8: Differentiate \( V \) with Respect to \( T \) Now, we differentiate \( V \) with respect to \( T \): \[ \frac{dV}{dT} = \frac{d}{dT} \left( \frac{RT^2}{a} \right) = \frac{2RT}{a} \] ### Step 9: Substitute \( \frac{dV}{dT} \) Back into the Equation for \( C \) Substituting \( \frac{dV}{dT} \) back into the equation for \( C \): \[ C = C_V + P \left( \frac{2RT}{a} \right) \] ### Step 10: Substitute \( P \) into the Equation Substituting \( P = \frac{a}{T} \): \[ C = C_V + \frac{a}{T} \cdot \frac{2RT}{a} \] This simplifies to: \[ C = C_V + 2R \] ### Step 11: Calculate \( C_V \) for a Monoatomic Gas For a monoatomic gas, the molar specific heat at constant volume \( C_V \) is: \[ C_V = \frac{3R}{2} \] ### Step 12: Final Calculation Substituting \( C_V \) into the equation for \( C \): \[ C = \frac{3R}{2} + 2R = \frac{3R}{2} + \frac{4R}{2} = \frac{7R}{2} \] ### Final Answer Thus, the molar specific heat of the process \( P = \frac{a}{T} \) for a monoatomic gas is: \[ C = \frac{7R}{2} \]

To find the molar specific heat of the process defined by \( P = \frac{a}{T} \) for a monoatomic gas, we can follow these steps: ### Step 1: Define Molar Specific Heat The molar specific heat \( C \) is defined as the amount of heat added per unit temperature change. Mathematically, it can be expressed as: \[ C = \frac{dQ}{dT} \] ...
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Knowledge Check

  • Molar specific heat at constant volume C_v for a monatomic gas is

    A
    `3/2`R
    B
    `5/2`R
    C
    3R
    D
    2R
  • One mole of an ideal monoatomic gas undergoes a process as shown in the figure. Find the molar specific heat of the gas in the process. R is a gas constant.

    A
    `(3R)/(4)`
    B
    `R/2`
    C
    `R/3`
    D
    `(2R)/(3)`
  • Graph for specific heat at constant volume for a monoatomic gas.

    A
    B
    C
    D
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