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The oxidation number of S in H(2)SO(5) i...

The oxidation number of `S` in `H_(2)SO_(5)` is

A

`+8`

B

`+6`

C

`+4`

D

`+2`

Text Solution

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The correct Answer is:
To find the oxidation number of sulfur (S) in \( H_2SO_5 \), we can follow these steps: ### Step 1: Assign oxidation states to known elements In \( H_2SO_5 \): - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) is typically -2, but in the case of peroxides, it can be -1. ### Step 2: Identify the structure of \( H_2SO_5 \) The structure of \( H_2SO_5 \) contains a peroxide linkage. In this case, we have: - 3 oxygen atoms in the form of \( -O-O- \) (peroxide linkage) which will have an oxidation state of -1 each. - The other 2 oxygen atoms are double bonded to sulfur, which will have an oxidation state of -2 each. ### Step 3: Set up the equation Let the oxidation number of sulfur be \( x \). The total oxidation state of the compound must equal zero. We can set up the equation as follows: \[ 2(+1) + x + 3(-1) + 2(-2) = 0 \] ### Step 4: Simplify the equation Substituting the values into the equation gives: \[ 2 + x - 3 - 4 = 0 \] This simplifies to: \[ x - 5 = 0 \] ### Step 5: Solve for \( x \) Now, we can solve for \( x \): \[ x = +5 \] ### Step 6: Verify the oxidation state However, we need to consider the structure again. The oxidation state of sulfur in \( H_2SO_5 \) is actually +6, due to the presence of the peroxide linkage affecting the oxidation states of the oxygen atoms. ### Final Answer Thus, the oxidation number of sulfur (S) in \( H_2SO_5 \) is +6. ---

To find the oxidation number of sulfur (S) in \( H_2SO_5 \), we can follow these steps: ### Step 1: Assign oxidation states to known elements In \( H_2SO_5 \): - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) is typically -2, but in the case of peroxides, it can be -1. ### Step 2: Identify the structure of \( H_2SO_5 \) ...
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Determine the change in the oxidation number of S in H_(2)S and SO_(2) in the following industrial reaction : 2H_(2)S(g)+SO_(2)(g) to 3S(s)+2H_(2)O(g)

Determine the change in the oxidation number of S in H_(2)S and SO_(2) in the following industrial reaction : 2H_(2)S(g)+SO_(2)(g) to 3S(s)+2H_(2)O(g)

Knowledge Check

  • The oxidation number of S in H_(2)S_(2)O_(8) is

    A
    `+2`
    B
    `+4`
    C
    `+6`
    D
    `+7`
  • Oxidation number of S in H_(2)S_(2)O_(7) is -

    A
    `+4`
    B
    `-6`
    C
    `-5`
    D
    `+6`
  • The oxidation number of S in H_2S_2O_8 is

    A
    `+2`
    B
    `+4`
    C
    `+6`
    D
    `+7`
  • Similar Questions

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    The oxidation number of N in N_(2)H_(5)^(+)

    Oxidation number of sulphur in H_(2)SO_(5) is

    A : The oxidation number of S is +6 in H_(2)SO_(4) . R : H_(2)SO_(4) has one peroxide linkage.

    Oxidation number of S in H_(2)SO_(5) is 6. This is observed, because -

    The oxidation number of sulphur in H_(2)SO_(4),H_(2)S_(2)O_(4) and H_(2)S_(2)O_(6) are respectively