Home
Class 11
CHEMISTRY
A compound of vanadium has a magnetic ...

A compound of vanadium has a magnetic moment of `1.73BM` Work out the electronic configuration of vanadius in the compound

Text Solution

Verified by Experts

The magnitude of moment `(mu)` of a compound species ion is given by
`mu = sqrt(n(n+ 2))BM`
(n is the number of unpaired electron BM is the unit of magnitude moment in bohr magneton)
`:. 1.73 = sqrt(n(n + 2))`
ON solving for r we get `n = 1` This mean that vandium ion `(Z = 23)` in the compound has one ampaired electromnm `3d `

So electronic configuration must be
`1s^(2)2s^(2)2p^(6)3s^(2)3p^(6)3d^(6)`
i.e. vanadium exies `V^(3+)` ion in the compound since the ground state electronic configuration of `_(23)V` is
`1s^(2)2s^(2)2p^(2)3s^(2)3p^(6)3d^(8)4s^(2)`
`3d
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY|Exercise Exercises (Subjective)|52 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY|Exercise Exercises Linked Comprehension|50 Videos
  • APPENDIX - INORGANIC VOLUME 1

    CENGAGE CHEMISTRY|Exercise chapter-7 Single correct answer|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY|Exercise Archives Subjective|15 Videos

Similar Questions

Explore conceptually related problems

A compound of variadium has a magnetic moment of 173 BM work out the electronic configuration of the vanadium in the compound.

A compound of vanadium has a magnetic moment of 1.73 BM, Work out the electronic configuration of the vanadium ion in the compound. (V = 23)

Knowledge Check

  • A compound of vanadium has a magnetic moment of 1.73 BM. The electronic configuration of vanadium ion in the compound is:

    A
    `[Ar]3d^(2)`
    B
    `[Ar]3d^(1)4s^(0)`
    C
    `[Ar]3d^(3)`
    D
    `[Ar]3d^(0)4s^(1)`
  • A compound of vanadium has a magnetic moment of 1.73 BM . What will be the electronic configurations:

    A
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(6) 3d^(1)`
    B
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(6) 3d^(2)`
    C
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(6) 3d^(3)`
    D
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(6) 3d^(4)`
  • Comprehension # 1 Read the following rules and answer the questions at the end of it. Electrons in various suborbits of an filled in increasing order to their energies. Pairing of electrons in various orbitals of a suborbit takes places only after each orbital is half-filled. No two electrons in an atom can have the same set of quantum number. A compound of vanadium has a magnetic moment of 1.73 BM . Electronic configuration of the vanadium ion in the compound is :

    A
    `[Ar]4s^(0)3d^(1)`
    B
    `[Ar]4s^(2)3d^(3)`
    C
    `[Ar]4s^(1)3d^(0)`
    D
    `[Ar]4s^(0)3d^(5)`
  • Similar Questions

    Explore conceptually related problems

    A compound of vanadium possesses a magnetic moment of 1.73BM . The oxidation state of vanadium in this compounds is:

    A compound of vanadium has a magneitc moment (mu) of 1.73 BM . If the vanadium ion in the compound is present as V^(x+) , then, the value of x is ?

    The maximum magnetic moment is shown by the ion with electronic configuration

    A compound of vanadium chloride has spin only magnetic moment of 1.73 BM. Its formula is

    A compound of vanadium has a magnetic moment (mu) of 1.73 BM. If the vanadium ion in the compound is present as V^(x+) then, the value of x is ?