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The standared enthalpies of formation at...

The standared enthalpies of formation at `298K` for `C C1(g), H_(2)O(g), CO_(2)(g)` and `HC1(g)` are `-106.7, -241.8, -393.7`, and `-92.5kJ mol^(-1)`, respectively. Calculate `DeltaH^(Theta)underset(298K)` for the reaction
`C C1_(4)(g) +2H_(2)O(g) rarr CO_(2)(g) +4HCI_(g)`

Text Solution

Verified by Experts

The enthalpy change of the given reaction will be given as
`DeltaH^(Theta) (CO_(2),g) +4Delta_(f)H^(Theta) (HCI,g)`
`- Delta_(f)H^(Theta) (C CI_(4),g) -2Delta_(f)H^(Theta) (H_(2)O, g)`
` =(-393.7-4 xx 92.5 + 106.7+2 xx 241.8) kJ mol^(-1)`
`=- 173.4 kJ mol^(-1)`
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The standard heats of formation at 298 K for C Cl_(4)(g), H_(2)O(g), CO_(2)(g) and HCl (g) are - 25.5, -57.8, -94.1 and -22.1 kcal per mole respectively. Calculate DeltaH^(@) at 298 K for the reaction, C Cl_(4)(g)+2H_(2)O(g) to CO_(2)(g)+4HCl(g)

Knowledge Check

  • At 298 K, the heats of formation fo C Cl_(4) (g), H_(2)O(g), CO_(2)(g) and HCl(g) are -25, -57, -94 and -22 K.cal mol^(-1) respectively. The DeltaH of the reaction: C Cl_(4)(g) +2H_(2)O rarr CO_(2) (g) +4HCl(g)

    A
    `-43` K. cal
    B
    `+72` K.cal
    C
    `14` K.cal
    D
    `-125` K.cal
  • The DeltaH^(@) for CO_(2)(g), CO(g) and H_(2)O(g) are -393.5, -110.5 and -241.8 kJ mol^(-1) respectively.The standard enthalpy change (in kJ) for the reaction : CO_(2)(g) + H_(2)(g) to CO(g) + H_(2)O(g) is

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    `524.1`
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    `41.2`
    C
    `-262.5`
    D
    `-41.2`
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