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Ammonium chloride dissociates as, NH(4...

Ammonium chloride dissociates as,
`NH_(4)Cl(g) hArr NH_(3)(g)+HCl(g)`
The vapour density becomes half the initial value when degree of dissociation is `0.5`.

Answer

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Solid Ammonium carbamate dissociates as: NH_(2)COONH_(4)(s)hArr2NH_(3)(g)+CO_(2)(g). In a closed vessel, solid ammonium carbonate is in equilibrium with its dissociation products. At equilibrium, ammonia is added such that the partial pressure of NH_(3) at new equilibrium now equals the original total pressure. Calculate the ratio of total pressure at new equilibrium to that of original total pressure. Also find the partial pressure of ammonia gas added.

The vapour density of fully dissociated NH_(4)Cl would be

Knowledge Check

  • NH_(4)Cl(s) rarr NH_(3)(g)+HCl(g) when the above reaction occurs, the entropy

    A
    Remains same
    B
    Decreases
    C
    Increases
    D
    None of the above
  • The vapour density of completely dissociated NH_(4)Cl is

    A
    double than that of `NH_(4)Cl`
    B
    half than that of `NH_(4)Cl`
    C
    same as that of `NH_(4)Cl`
    D
    determined by the amount of solid `NH_(4)Cl` taken
  • NH_4 Cl hArr NH_3 + HCl reaction is called

    A
    lonic dissociation
    B
    thermal decomposition
    C
    thermal dissociation
    D
    double decomposition
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