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Graph between log k and 1//T [k rate con...

Graph between `log k` and `1//T` [`k` rate constant `(s^(-1))` and `T` and the temperature `(K)`] is a straight line with `OX =5, theta = tan^(-1) (1//2.303)`. Hence `-E_(a)` will be

A

`2.303 xx 2 cal`

B

`2//2.303 cal`

C

`2 cal`

D

None

Text Solution

Verified by Experts

The correct Answer is:
C

`logk=logA-(E_(a))/(2.303 RT)(y=c+mx)`
Slope `=(-E_(a))/(2.303R)=(1)/(2.303)(given)(tan theta=(1)/(2.303))`
`-E_(a)= 2.303Rxxslope`
`=2.303xx(R )/(2.303)=R=2 cal`
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The graph between log k and 1/T[K is rate constant ( sec^(-1) ) and T the temperature (K)] is a straight line with OX=5 and theta=tan^(-1)(-1/2.303) .Calculate the value of E_a is cal. ?

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Knowledge Check

  • Graph between log k and 1 // T [k is rate constant ( s^(-1) ) and T the temperature (K)] is a straight line with OX = 5, theta = tan^(-1)(1 // 2.303) . Hence- E_(a) will be

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