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The specific rate constant of a first or...

The specific rate constant of a first order reaction depends on the

A

Concentration of the reactant

B

Concentration of the Product

C

Time

D

Temperature

Text Solution

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The correct Answer is:
To solve the question regarding the specific rate constant of a first-order reaction, we can follow these steps: ### Step 1: Understand the concept of specific rate constant (k) The specific rate constant (k) is a proportionality constant in the rate law of a chemical reaction. For a first-order reaction, the rate of reaction is directly proportional to the concentration of one reactant. ### Step 2: Identify the factors affecting the rate constant The specific rate constant (k) is influenced by several factors, including: - Temperature - Activation energy - The nature of the reactants ### Step 3: Analyze the relationship with temperature For most reactions, the rate constant increases with an increase in temperature. This is described by the Arrhenius equation: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) = rate constant - \( A \) = frequency factor - \( E_a \) = activation energy - \( R \) = universal gas constant - \( T \) = temperature in Kelvin ### Step 4: Conclude the dependence of k From the analysis, we can conclude that for a first-order reaction, the specific rate constant (k) primarily depends on temperature. It does not depend on the concentration of reactants or the order of the reaction itself. ### Final Answer The specific rate constant of a first-order reaction depends on temperature. ---
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The specific rate constant for a first order reaction is 1 times 10^–3 sec^–1 . If the initial concentration of the reactant is 0.1 mole/lt, the rate of reaction mol l^–1 sec^–1 is:

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Knowledge Check

  • The specific reaction rate of a first order reaction depends on the :

    A
    Concentrations of reactants
    B
    Concentrations of products
    C
    Time of reaction
    D
    Temperature of reactions
  • The unit of rate constant for a first order reaction

    A
    `L^2"mol"^(-2)s^(-1)`
    B
    `s^(-1)`
    C
    `"mol"L^(-1)s^(-1)`
    D
    `L "mol"^(-1) s^(-1)`
  • Which factor affect the specific rate constant of a first order reaction ?

    A
    Time for completion of reaction
    B
    Concentration of the reactants
    C
    Concentration of the products
    D
    Temperature of reaction
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