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The rate of reaction A + B rarr Product ...

The rate of reaction `A + B rarr` Product is given by the equation `r = k[A][B]`. If `B` is taken in large excess, the order of the reaction would be

A

`a. 2`

B

`b. 1`

C

`c. 0`

D

d. Unpredictable

Text Solution

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The correct Answer is:
To determine the order of the reaction when reactant B is taken in large excess, we can follow these steps: ### Step 1: Understand the Rate Equation The given rate equation for the reaction \( A + B \rightarrow \text{Product} \) is: \[ r = k[A][B] \] where \( r \) is the rate of the reaction, \( k \) is the rate constant, and \([A]\) and \([B]\) are the concentrations of reactants A and B, respectively. ### Step 2: Consider B in Large Excess When reactant B is taken in large excess, its concentration remains relatively constant throughout the reaction. This means that the change in concentration of B is negligible compared to A. ### Step 3: Simplify the Rate Expression Since \([B]\) is constant, we can denote it as a new constant \( [B]_0 \). Thus, the rate expression can be rewritten as: \[ r = k[A][B] \approx k[A][B]_0 \] Here, \( k[B]_0 \) can be treated as a new effective rate constant \( k' \): \[ r = k'[A] \] where \( k' = k[B]_0 \). ### Step 4: Determine the Order of the Reaction In this new rate expression \( r = k'[A] \), the rate of the reaction depends only on the concentration of A. The order of the reaction with respect to A is 1, since the rate is directly proportional to the concentration of A. ### Conclusion Therefore, when B is taken in large excess, the order of the reaction is 1. ### Final Answer The order of the reaction is 1. ---

To determine the order of the reaction when reactant B is taken in large excess, we can follow these steps: ### Step 1: Understand the Rate Equation The given rate equation for the reaction \( A + B \rightarrow \text{Product} \) is: \[ r = k[A][B] \] where \( r \) is the rate of the reaction, \( k \) is the rate constant, and \([A]\) and \([B]\) are the concentrations of reactants A and B, respectively. ...
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Knowledge Check

  • The rate of reaction, A+B rarr Products, is given by the equation r = k[A] [B]. If B is taken in large excess, the order of the reaction would be

    A
    2
    B
    1
    C
    0
    D
    unpredictable
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    A
    0
    B
    1
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    D
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