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A compound C(6)H(14)O(2) has two tertiar...

A compound `C_(6)H_(14)O_(2)` has two tertiary alcoholic groups . The IUPAC name of this compound is

A

2,3-dimethyl -1, 2 - butanediol

B

3,3-dimethyl - 1 , 2 - butanediol

C

2,3-dimethyl-2 , 3-butanediol

D

2-methyl-2 , 3- pentanediol .

Text Solution

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The correct Answer is:
To determine the IUPAC name of the compound with the formula \( C_6H_{14}O_2 \) that contains two tertiary alcoholic groups, we can follow these steps: ### Step 1: Understand the Structure We know that a tertiary alcohol is one where the carbon atom attached to the hydroxyl group (–OH) is also bonded to three other carbon atoms. Therefore, we are looking for a structure where both –OH groups are attached to tertiary carbons. ### Step 2: Determine the Carbon Skeleton Given the molecular formula \( C_6H_{14}O_2 \), we can start by sketching a carbon chain that can accommodate two –OH groups. A suitable carbon skeleton for this compound could be a butane chain with two additional methyl groups. ### Step 3: Construct the Compound We can construct the compound as follows: - Start with a butane backbone (4 carbon atoms). - Add two methyl groups on the second and third carbons. - Attach the –OH groups to the second and third carbons. The structure can be represented as: ``` CH3 | CH3-C-CH-CH3 | | OH OH ``` ### Step 4: Number the Carbon Chain Number the carbon chain from the end nearest to the first –OH group: 1. Carbon 1: CH3 2. Carbon 2: C(OH) with a methyl group 3. Carbon 3: C(OH) with a methyl group 4. Carbon 4: CH3 This gives us the numbering: - C1: CH3 - C2: OH and CH3 (methyl) - C3: OH and CH3 (methyl) - C4: CH3 ### Step 5: Write the IUPAC Name The IUPAC name is derived from the structure: - The longest carbon chain has 4 carbons (butane). - There are two –OH groups, so we use "diol." - The methyl groups at positions 2 and 3 give us "dimethyl." Thus, the IUPAC name of the compound is **2,3-dimethyl-2,3-butanediol**. ### Final Answer The IUPAC name of the compound \( C_6H_{14}O_2 \) with two tertiary alcoholic groups is **2,3-dimethyl-2,3-butanediol**.

To determine the IUPAC name of the compound with the formula \( C_6H_{14}O_2 \) that contains two tertiary alcoholic groups, we can follow these steps: ### Step 1: Understand the Structure We know that a tertiary alcohol is one where the carbon atom attached to the hydroxyl group (–OH) is also bonded to three other carbon atoms. Therefore, we are looking for a structure where both –OH groups are attached to tertiary carbons. ### Step 2: Determine the Carbon Skeleton Given the molecular formula \( C_6H_{14}O_2 \), we can start by sketching a carbon chain that can accommodate two –OH groups. A suitable carbon skeleton for this compound could be a butane chain with two additional methyl groups. ...
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