Home
Class 12
CHEMISTRY
A compound C(6)H(14)O(2) has two tertiar...

A compound `C_(6)H_(14)O_(2)` has two tertiary alcoholic groups . The IUPAC name of this compound is

A

2,3-dimethyl -1, 2 - butanediol

B

3,3-dimethyl - 1 , 2 - butanediol

C

2,3-dimethyl-2 , 3-butanediol

D

2-methyl-2 , 3- pentanediol .

Text Solution

AI Generated Solution

The correct Answer is:
To determine the IUPAC name of the compound with the formula \( C_6H_{14}O_2 \) that contains two tertiary alcoholic groups, we can follow these steps: ### Step 1: Understand the Structure We know that a tertiary alcohol is one where the carbon atom attached to the hydroxyl group (–OH) is also bonded to three other carbon atoms. Therefore, we are looking for a structure where both –OH groups are attached to tertiary carbons. ### Step 2: Determine the Carbon Skeleton Given the molecular formula \( C_6H_{14}O_2 \), we can start by sketching a carbon chain that can accommodate two –OH groups. A suitable carbon skeleton for this compound could be a butane chain with two additional methyl groups. ### Step 3: Construct the Compound We can construct the compound as follows: - Start with a butane backbone (4 carbon atoms). - Add two methyl groups on the second and third carbons. - Attach the –OH groups to the second and third carbons. The structure can be represented as: ``` CH3 | CH3-C-CH-CH3 | | OH OH ``` ### Step 4: Number the Carbon Chain Number the carbon chain from the end nearest to the first –OH group: 1. Carbon 1: CH3 2. Carbon 2: C(OH) with a methyl group 3. Carbon 3: C(OH) with a methyl group 4. Carbon 4: CH3 This gives us the numbering: - C1: CH3 - C2: OH and CH3 (methyl) - C3: OH and CH3 (methyl) - C4: CH3 ### Step 5: Write the IUPAC Name The IUPAC name is derived from the structure: - The longest carbon chain has 4 carbons (butane). - There are two –OH groups, so we use "diol." - The methyl groups at positions 2 and 3 give us "dimethyl." Thus, the IUPAC name of the compound is **2,3-dimethyl-2,3-butanediol**. ### Final Answer The IUPAC name of the compound \( C_6H_{14}O_2 \) with two tertiary alcoholic groups is **2,3-dimethyl-2,3-butanediol**.

To determine the IUPAC name of the compound with the formula \( C_6H_{14}O_2 \) that contains two tertiary alcoholic groups, we can follow these steps: ### Step 1: Understand the Structure We know that a tertiary alcohol is one where the carbon atom attached to the hydroxyl group (–OH) is also bonded to three other carbon atoms. Therefore, we are looking for a structure where both –OH groups are attached to tertiary carbons. ### Step 2: Determine the Carbon Skeleton Given the molecular formula \( C_6H_{14}O_2 \), we can start by sketching a carbon chain that can accommodate two –OH groups. A suitable carbon skeleton for this compound could be a butane chain with two additional methyl groups. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS|Exercise Structures Of Functional Groups|2 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS|Exercise Alcohols And Phenols|68 Videos
  • ALCOHOLS,PHENOLS AND ETHERS

    NCERT FINGERTIPS|Exercise Assertion And Reason|14 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    NCERT FINGERTIPS|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

Give the IUPAC name of the following compound : C_(2)H_(6)

IUPAC name of the compound (C_2H_5)_2NCH_3 is

Knowledge Check

  • The IUPAC name of the compound c is

    A
    (1) `5`-isobutylhept-`6`-enoic acid
    B
    (2) `5`-sec-butylhept-`6`-enoic acid
    C
    (3) `5`-tert-butylhept-`6`-enoic acid
    D
    (4) `5`-butylhept-`6`-enoic acid
  • A compound C_(6)H_(14)O_(2) has two tertiary groups. The IUPAC name of the compound is

    A
    `2,3`-dimethylbutane -`1,2`-diol
    B
    `2,3`-dimethylbutane -`2,3`-diol
    C
    `3,3`-dimethylbutane-`1,2`-diol
    D
    `2`-methylpantene-`2,3`-diol
  • A tetrahydric alcohol with the formula C_(5)H_(12)O_(4) has all of its alcoholic functions primary. The IUPAC name of the alcohol is

    A
    `2,2`-bis(hydroxmethyl) propane -`1,3`-diol
    B
    `1,2,3,4,5`-pentaneterol
    C
    `2`-methyl-`1,2,3,4`-butanetetraol
    D
    `1,2,3,4`-pentanetraol
  • Similar Questions

    Explore conceptually related problems

    A compound with molecular formula C_(6)H_(14) has two tertiary carbons. Its IUPAC name is

    The compound with molecular formula, C_(6)H_(14) has two tertiary carbons. Its IUPAC name is

    Which isomer of C_(6)H_(14) has two isopropyl groups

    Which compound is tertiary alcohol ?

    Oxidation of allyl alcohol with a peracid gives a compound of molecular formula C_(3)H_(6)O_(2) which contains an asymmetric carbon atom. The structure of the compound is