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NaCl((aq)) gives a white precipitate wit...

`NaCl_((aq))` gives a white precipitate with `AgNO_(3)` solution but `C Cl_(4) or CHCl_(3)` does not , because

A

NaCl is a covalent compound and forms AgCl as white ppt.

B

NaCl is an ionic compound and forms AgCl as white ppt.

C

`C Cl_(4) and CHCl_(3)` are ionic compound.

D

none of these.

Text Solution

Verified by Experts

The correct Answer is:
B

NaCl being an ionic compound and thus reacts with `AgNO_(3(aq))` to give ionic reaction , forming AgCl as white ppt. `C Cl_(4) and CHCl_(3)` being covalent do not furnish `Cl^(-)` ions in solution.
`NaCl + AgNO_(3) to AgCl + NaNO_(3)`
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Knowledge Check

  • AgNO_(3) gives red precipitate with

    A
    Nal
    B
    KCI
    C
    `NaNO_(3)`
    D
    `Na_(2)CrO_(4)`
  • C CI_(4) cannot give precipitate with AgNO_(3) due to.

    A
    Formation of complex with `AgNO_(3)`
    B
    Evolution of `CI_(2)` gas
    C
    Chloride ion is not formed
    D
    `AgNO_(3)` does not give silver ion .
  • Statement-1. Co(NH_(3))_(2)Cl_(3) gives white precipitate with AgNO_(3) solution. Statement-2. Chlorine is not present in the ionising sphere.

    A
    Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-8
    B
    Statement-1 is True, Statement is 2 is True , Statement-2 is NOT a correct explanation for Statement-8
    C
    Statement-1 is True, Statement-2 is False
    D
    Statement-1 is False, Statement-2 is True
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    NaBr gives pale yellow precipitate with AgNO_(3) solution but CBr_(4) does not. Why ?

    Iodoform gives a precipitate with AgNO3 on heating but chloroform does not because -

    CHCl_(3) does not give white ppt. with AgNO_(3) because it:

    C Cl_4 does not give a precipitate with AgNO_(3) . Its reason is:

    Assertion: [ClCl_(3)(NH_(3))_(3)] does not give white precipitate with AgNO_(3) solution. Reason: [CoCl_(3)(NH_(3))_(3)] complex is optically inactive.