Home
Class 12
CHEMISTRY
The order of stability for the conformat...

The order of stability for the conformations of n-butane among these is
`{:("anti" , I),("gauche" , II),("eclipsed (partial)" , III),("eclipsed (fully)" , IV):}`

A

`I>II>III>IV`

B

`IV>III>II>I`

C

`III>II>I>IV`

D

`II>III>I>IV`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of stability for the conformations of n-butane, we will analyze the different conformations: anti, gauche, eclipsed (partial), and eclipsed (fully). ### Step-by-Step Solution: 1. **Identify the Conformations of n-butane**: - n-butane has several conformations due to rotation around the carbon-carbon single bonds. The key conformations to consider are: - Anti (staggered) - Gauche (staggered) - Eclipsed (partial) - Eclipsed (fully) 2. **Draw the Anti Conformation**: - In the anti conformation, the two bulky methyl (CH3) groups are opposite to each other. This configuration minimizes steric hindrance and torsional strain, making it the most stable conformation. 3. **Draw the Gauche Conformation**: - In the gauche conformation, the two bulky methyl groups are adjacent to each other (60° dihedral angle). This conformation has some steric strain due to the proximity of the bulky groups, but it is more stable than the eclipsed conformations. 4. **Draw the Eclipsed (Partial) Conformation**: - In the partial eclipsed conformation, one methyl group is eclipsed with a hydrogen atom. This configuration has more torsional strain than the gauche conformation but less than the fully eclipsed conformation. 5. **Draw the Eclipsed (Fully) Conformation**: - In the fully eclipsed conformation, the two bulky methyl groups are directly overlapping (0° dihedral angle). This arrangement creates the highest steric strain and torsional strain, making it the least stable conformation. 6. **Rank the Stability**: - Based on the analysis: - Most stable: Anti (1) - Next: Gauche (2) - Then: Eclipsed (partial) (3) - Least stable: Eclipsed (fully) (4) ### Final Order of Stability: The order of stability for the conformations of n-butane is: 1. Anti (I) 2. Gauche (II) 3. Eclipsed (partial) (III) 4. Eclipsed (fully) (IV)

To determine the order of stability for the conformations of n-butane, we will analyze the different conformations: anti, gauche, eclipsed (partial), and eclipsed (fully). ### Step-by-Step Solution: 1. **Identify the Conformations of n-butane**: - n-butane has several conformations due to rotation around the carbon-carbon single bonds. The key conformations to consider are: - Anti (staggered) - Gauche (staggered) ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALKANES

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise EXERCISE 2|20 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|21 Videos
  • ALKYL HALIDE

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|25 Videos

Similar Questions

Explore conceptually related problems

The order of stability of the species (i), (ii) and (iii) is

How many gauche conformations are possible for n- butane ?

Knowledge Check

  • The dihedral angle of the most stable anti-conformation of n-butane is

    A
    `180^(@)`
    B
    `120^(@)`
    C
    `60^(@)`
    D
    `0^(@)`
  • Increasing order of stability among the three main conformations of 2-Fluroethanol is :

    A
    eclipse, gauche, anti
    B
    gauche, eclipse, anti
    C
    eclipse, anti, gauche
    D
    anti, gauche, esclipse
  • Among the following , the most stable conformation of n-butane is

    A
    B
    C
    D
  • Similar Questions

    Explore conceptually related problems

    How many gauche conformations are possible for n-butane?

    Increasing order of stability among thr three main conformation (i.e. eclipse, anti, gauche) of ethylene glycol is :

    Increasing order of stability among the three main conformation (i.e., eclips, anti,gauche) of enthalpy glycol is

    Which will be the correct stability order of the different conformations of n - butane ?

    Increasing order of stability among the three main conformations (i.e. , eclipse, anti, gauche ) of 2-fluoroethanol is