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The order of stability for the conformat...

The order of stability for the conformations of n-butane among these is
`{:("anti" , I),("gauche" , II),("eclipsed (partial)" , III),("eclipsed (fully)" , IV):}`

A

`I>II>III>IV`

B

`IV>III>II>I`

C

`III>II>I>IV`

D

`II>III>I>IV`

Text Solution

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The correct Answer is:
To determine the order of stability for the conformations of n-butane, we will analyze the different conformations: anti, gauche, eclipsed (partial), and eclipsed (fully). ### Step-by-Step Solution: 1. **Identify the Conformations of n-butane**: - n-butane has several conformations due to rotation around the carbon-carbon single bonds. The key conformations to consider are: - Anti (staggered) - Gauche (staggered) - Eclipsed (partial) - Eclipsed (fully) 2. **Draw the Anti Conformation**: - In the anti conformation, the two bulky methyl (CH3) groups are opposite to each other. This configuration minimizes steric hindrance and torsional strain, making it the most stable conformation. 3. **Draw the Gauche Conformation**: - In the gauche conformation, the two bulky methyl groups are adjacent to each other (60° dihedral angle). This conformation has some steric strain due to the proximity of the bulky groups, but it is more stable than the eclipsed conformations. 4. **Draw the Eclipsed (Partial) Conformation**: - In the partial eclipsed conformation, one methyl group is eclipsed with a hydrogen atom. This configuration has more torsional strain than the gauche conformation but less than the fully eclipsed conformation. 5. **Draw the Eclipsed (Fully) Conformation**: - In the fully eclipsed conformation, the two bulky methyl groups are directly overlapping (0° dihedral angle). This arrangement creates the highest steric strain and torsional strain, making it the least stable conformation. 6. **Rank the Stability**: - Based on the analysis: - Most stable: Anti (1) - Next: Gauche (2) - Then: Eclipsed (partial) (3) - Least stable: Eclipsed (fully) (4) ### Final Order of Stability: The order of stability for the conformations of n-butane is: 1. Anti (I) 2. Gauche (II) 3. Eclipsed (partial) (III) 4. Eclipsed (fully) (IV)

To determine the order of stability for the conformations of n-butane, we will analyze the different conformations: anti, gauche, eclipsed (partial), and eclipsed (fully). ### Step-by-Step Solution: 1. **Identify the Conformations of n-butane**: - n-butane has several conformations due to rotation around the carbon-carbon single bonds. The key conformations to consider are: - Anti (staggered) - Gauche (staggered) ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALKANES-EXERCISE 2
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  9. A mixture of ethyl iodide and n-propyl iodide is subjected to Wurtz re...

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  10. The reagent used for the conversion CH3CH2COOH to CH3CH2CH3 , is

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  11. Both methane and ethane may be obtained by suitable one step reaction ...

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  12. Arrange the following in decreasing order of their boiling points. (...

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  14. The highest boiling point is expected for:

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  15. Of the five isomeric hexanes, the isomer which can give two monochlori...

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  16. On mixing certain alkane with chlorine and irradiating it with ultravi...

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  17. Which of the following reaction is not correct ?

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  18. Which of the following alkanes can be easily sulphonated?

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  19. Using C2H5Cl//Na by Wurtz reaction in addition to C4H10, C2H4 " and " ...

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  20. The alkane is not obtained from

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  21. Roversetunderset(||)(O)(C)CH3 (ketone) can be reduced to RCH2CH3 (alka...

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