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Which of the following 0.1 M complex ...

Which of the following 0.1 M complex compound solutions will have the minimum electrical conductivity ?

A

Hexammine platinum (IV ) chloride

B

Terammine chloroido platinum (IV ) chloride

C

Pentamine chlorido platinum (IV ) chloride

D

Tromminetrchlorido platinum (IV ) chloride

Text Solution

Verified by Experts

The correct Answer is:
D
(d) The formula of the given complex are as follows :
(a) Hexammineplatinum (iv ) chloride
`[Pt (NH_(3))_(6) ]Cl_(4) `
(b) pentaminetaammine platinum (IV ) chloride
`[Pt(NH_(3))_(5) ]Cl_(3) `
(c ) tetramminedichorido platinum (IV ) choride
`[Pt(NH_(3))_(4) Cl_(2)]Cl_(2) `
( D) triamminetrichloride platium (IV ) chloride
` [Pt(NH_(3)_(3)) Cl_(3)]Cl`
in aqueous solution the complex ionises as
` [Pt(NH_(3))_(3)]ClhArr [Pt(NH_(3)Cl_(3)]^(+)+Cl^(-)`
Triamminetrichlorido platinum (IV) gives the minimum number of ions in the solution .hence , it has the minimum electrical conductivity .
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