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The melting point and solubility in wate...

The melting point and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain. Higher the polarity of a group , more is its solubitlity in water.

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Amino acids are dipolar in nature `(NH_3-CHR-COO^-)` and have strong dipolar interactions. Therefore, these have high melting point . When dissolved in water, these form hydrogen bonds with water molecules, therefore , these are soluble in water .(except at isoelectric point, where they have atleat solubility) in case of halo acids, these are not dipolar. Only their carboxyl group is involved in hydrogen bonding, not the halogen atom. Therefore, halo acids. have lower melting points and lesser solubility than amino acids
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Knowledge Check

  • (A) The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. (R) Amino group of amino acids can form hydrogen bonds but halogen of halo acids can not form hydrogen bonds.

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
    Both (A) and (R) are false
  • At its melting point ice is lighter than water because

    A
    `H_(2)O` molecules are more closely packed in solid state
    B
    Ice crystals have hollow hexagonal arrange-ment of `H_(2)O` molecules shrinks in size
    C
    On melting of ice the `H_(2)O` molecules shrinks in size
    D
    Ice forms mostly heavy water on first melting
  • (A) Boiling points of acids are higher than the corresponding alcohols. (R) Esters are hydrolysed with dilute mineral acids to give carboxylic acids.

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
    Both (A) and (R) are false
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