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Which has the most stable +2 oxidation s...

Which has the most stable `+2` oxidation state ?

A

`Sn`

B

`Fe`

C

`Pb`

D

`Ag`

Text Solution

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The correct Answer is:
To determine which element has the most stable +2 oxidation state among the given options, we will analyze the oxidation states of each element based on their group in the periodic table and the effects that influence their stability. ### Step-by-Step Solution: 1. **Identify the Elements**: The elements mentioned are tin (Sn), lead (Pb), iron (Fe), and silver (Ag). 2. **Group Classification**: - Tin (Sn) and Lead (Pb) belong to Group 14 of the periodic table. - Iron (Fe) is a transition metal in the d-block. - Silver (Ag) is also a transition metal. 3. **Oxidation States**: - **Iron (Fe)**: The +2 oxidation state (Fe²⁺) is common, but it can also exist in the +3 oxidation state (Fe³⁺). The stability of these states depends on the electron configuration. Fe²⁺ has the configuration of 3d⁶, which is less stable compared to fully filled or half-filled configurations. - **Silver (Ag)**: The +1 oxidation state (Ag⁺) is more stable than the +2 oxidation state (Ag²⁺). Silver tends to lose only one electron to achieve a stable configuration. - **Tin (Sn)**: In Group 14, Sn can exhibit +2 and +4 oxidation states. However, the +2 state is less stable compared to lead. - **Lead (Pb)**: As we move down Group 14, the +2 oxidation state becomes more stable due to the inert pair effect. Lead (Pb) has a +2 oxidation state that is more stable than that of tin. 4. **Inert Pair Effect**: This effect refers to the tendency of the outermost s-electrons to remain non-bonding in heavier elements. For lead, this means that the +2 oxidation state is favored over the +4 state. 5. **Conclusion**: Among the given elements, lead (Pb) has the most stable +2 oxidation state due to its position in the periodic table and the inert pair effect. ### Final Answer: Lead (Pb) has the most stable +2 oxidation state. ---

To determine which element has the most stable +2 oxidation state among the given options, we will analyze the oxidation states of each element based on their group in the periodic table and the effects that influence their stability. ### Step-by-Step Solution: 1. **Identify the Elements**: The elements mentioned are tin (Sn), lead (Pb), iron (Fe), and silver (Ag). 2. **Group Classification**: - Tin (Sn) and Lead (Pb) belong to Group 14 of the periodic table. ...
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Knowledge Check

  • Which has most stable +2 oxidation state :

    A
    Sn
    B
    Pb
    C
    Fe
    D
    Ag
  • The most stable oxidation state of boron is

    A
    `+3`
    B
    `+1`
    C
    `-3`
    D
    `-1`
  • Most stable oxidation state of Pa is

    A
    `+2`
    B
    `+3`
    C
    `+5`
    D
    `+7`
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