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Solubility of an ionic compound in water...

Solubility of an ionic compound in water is mainly dependent on:
a.Lattice enthalpy , b. Hydration enthalphy
Both these factors oppose each other and the resultant of these determines the solubility of an ionic compound in water. If lattce enthalpy has greater value, the compound is less soluble.
In case hydration enthalpy has greater value, the compound is highly soluble in water.
Which of the following is less soluble in water?

A

`Mg(OH)_(2)`

B

`Ca(OH)_(2)`

C

`Sr(OH)_(2)`

D

`Ba(OH)_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Solubility of alkaline earth metal hydroxides increases down the group `(darr)`.
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Solubility of an ionic compound in water is mainly dependent on: a.Lattice enthalpy , b. Hydration enthalphy Both these factors oppose each other and the resultant of these determines the solubility of an ionic compound in water. If lattce enthalpy has greater value, the compound is less soluble. In case hydration enthalpy has greater value, the compound is highly soluble in water. BeF_(2) is soluble in water while fluorides of other alkaline earth metals are insoluble because of:

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Knowledge Check

  • Solubility of an ionic compound in water is mainly dependent on: a.Lattice enthalpy , b. Hydration enthalphy Both these factors oppose each other and the resultant of these determines the solubility of an ionic compound in water. If lattce enthalpy has greater value, the compound is less soluble. In case hydration enthalpy has greater value, the compound is highly soluble in water. Which of the following is more soluble in water?

    A
    `MgSO_(4)`
    B
    `CaSO_(4)`
    C
    `SrSO_(4)`
    D
    `BaSO_(4)`
  • Solubility of an ionic compound in water is mainly dependent on: a.Lattice enthalpy , b. Hydration enthalphy Both these factors oppose each other and the resultant of these determines the solubility of an ionic compound in water. If lattce enthalpy has greater value, the compound is less soluble. In case hydration enthalpy has greater value, the compound is highly soluble in water. Compound is soluble in water if

    A
    Hydration enthalpy is greater than lattice enthalpy
    B
    Hydration enthalpy is less than lattice enthalpy
    C
    hydration enthalpy and lattice enthalpy are same
    D
    None of the above
  • Solubility of an ionic compound in water is mainly dependent on: a.Lattice enthalpy , b. Hydration enthalphy Both these factors oppose each other and the resultant of these determines the solubility of an ionic compound in water. If lattce enthalpy has greater value, the compound is less soluble. In case hydration enthalpy has greater value, the compound is highly soluble in water. Compound of alkaline earth metals are less soluble than alkali metals, due to:

    A
    Their high hydration enthalpy
    B
    Their high lattice enthalpy
    C
    Their increases covalent character
    D
    Their high ionisation enthalpy.
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