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Solid N2 O5 exists as NO2^(oplus) NO3^(Ө...

Solid `N_2 O_5` exists as `NO_2^(oplus) NO_3^(Ө)` and hence is called nitronium nitrate.
Choose the incorrect statement.

A

`NO_2` molecule is angular with `N-O` distance equal to intermediate distance between a single and a double bond.

B

In `N_2 O_4` the `N-N` bond length is longer than the usual `N-N` single bond distance.

C

`N_2 O` is a linear molecule and has a small dipole moment.

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
D
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NO_2^- is oxidised to N_2//NO_3^- by acidified KMnO_4

The complex [Fe(H_(2)O)_(5)NO]^(2+) is formed in the 'brown ring test' for nitrates. Choose the incorrect statement for the complex.

Knowledge Check

  • Solid N_2 O_5 exists as NO_2^(oplus) NO_3^(Ө) and hence is called nitronium nitrate. Which of the following statement is correct for the oxides of nitrogen ?

    A
    Dinitrogen trioxide dissolves in potassium hydroxide forming potassium nitrate.
    B
    Aqueous solution of nitrogen dioxide behaves both as a reducing agent and as an oxidising agent.
    C
    `NO_2` is non-planar.
    D
    Nitrous oxide is fairly soluble in cold water and turns blue litmus red.

  • Solid N_2O_5 is

    A
    Ionic
    B
    covalent
    C
    Coordinate covalent
    D
    Metallic

  • Solid N_2O_5 is -

    A
    lonic
    B
    Covalent
    C
    coordinate covalent
    D
    Metallic

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