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How many unpaired electrons are present ...

How many unpaired electrons are present in `NO` molecule ?

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To determine the number of unpaired electrons in the nitrogen monoxide (NO) molecule, we can follow these steps: ### Step 1: Determine the electronic configuration of nitrogen and oxygen - Nitrogen (N) has an atomic number of 7, so its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^3 \] - Oxygen (O) has an atomic number of 8, so its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^4 \] ### Step 2: Combine the electrons from nitrogen and oxygen - The total number of valence electrons in the NO molecule is: \[ \text{Total electrons} = \text{Electrons from N} + \text{Electrons from O} = 5 + 6 = 11 \] ### Step 3: Construct the molecular orbital diagram - In the molecular orbital theory, the 11 electrons will fill the molecular orbitals in the following order: - \( \sigma_{1s}^2 \) - \( \sigma_{1s}^2 \) - \( \sigma_{2s}^2 \) - \( \sigma_{2s}^2 \) - \( \sigma_{2p_z}^2 \) (bonding orbital) - \( \pi_{2p_x}^2 \) (bonding orbital) - \( \pi_{2p_y}^2 \) (bonding orbital) - \( \pi^*_{2p_x}^1 \) (antibonding orbital) ### Step 4: Count the unpaired electrons - From the filling of the molecular orbitals, we see that: - The \( \pi^*_{2p_x} \) orbital has 1 electron, which is unpaired. - Therefore, the total number of unpaired electrons in the NO molecule is: \[ \text{Number of unpaired electrons} = 1 \] ### Conclusion The NO molecule has **1 unpaired electron**. ---
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Knowledge Check

  • How many unpaired electrons are present in N_2^+ ?

    A
    1
    B
    2
    C
    3
    D
    4
  • How many unpaired electrons are present in Ni^(2+) ?

    A
    0
    B
    2
    C
    4
    D
    8
  • The magnetic moment of K_3[Fe(CN)_6] is found to be 1.7 B.M . How many unpaired electron(s) is/are present per molecule?

    A
    (a) `2`
    B
    (b) `3`
    C
    (c) `4`
    D
    (d) `1`
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