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How many unpaired electrons are present in `NO` molecule ?

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To determine the number of unpaired electrons in the nitrogen monoxide (NO) molecule, we can follow these steps: ### Step 1: Determine the electronic configuration of nitrogen and oxygen - Nitrogen (N) has an atomic number of 7, so its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^3 \] - Oxygen (O) has an atomic number of 8, so its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^4 \] ### Step 2: Combine the electrons from nitrogen and oxygen - The total number of valence electrons in the NO molecule is: \[ \text{Total electrons} = \text{Electrons from N} + \text{Electrons from O} = 5 + 6 = 11 \] ### Step 3: Construct the molecular orbital diagram - In the molecular orbital theory, the 11 electrons will fill the molecular orbitals in the following order: - \( \sigma_{1s}^2 \) - \( \sigma_{1s}^2 \) - \( \sigma_{2s}^2 \) - \( \sigma_{2s}^2 \) - \( \sigma_{2p_z}^2 \) (bonding orbital) - \( \pi_{2p_x}^2 \) (bonding orbital) - \( \pi_{2p_y}^2 \) (bonding orbital) - \( \pi^*_{2p_x}^1 \) (antibonding orbital) ### Step 4: Count the unpaired electrons - From the filling of the molecular orbitals, we see that: - The \( \pi^*_{2p_x} \) orbital has 1 electron, which is unpaired. - Therefore, the total number of unpaired electrons in the NO molecule is: \[ \text{Number of unpaired electrons} = 1 \] ### Conclusion The NO molecule has **1 unpaired electron**. ---
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CENGAGE CHEMISTRY-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Integer)
  1. Nitrogen forms how many oxides

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  2. How many lone pairs are present in nitrogen molecule ?

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  3. In group 15 elements, the number of unpaired electrons in valence shel...

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  4. How many P-O-P bonds are present in P4 O8 ?

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  5. In solid PCl5 molecule, how many P-Cl bonds are present in the cation ...

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  6. What is the basicity of pyrophosphoric acid ?

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  7. How many sigma-bonds are present in N2 O3 ?

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  8. When excess of ammonia and chlorine react, nitrogen and ammonium chlor...

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  9. What is the atomicit of phosphorous ?

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  10. How many N-O (sigma) bonds are present in N2 O5 ?

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  11. In P4 O10, how many oxygen atoms are bonded to each phosphorous atoms ...

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  12. How many unpaired electrons are present in NO molecule ?

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  13. The number of vacant orbitals in the valence shell of phosphorous is .

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  14. How many hydrogen bonds are formed by each H3 PO4 molecule ?

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  15. On hydrolysis, of calcium phosphide, how many moles of phosphine are f...

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  16. How many lone pairs are present in white phosphorous ?

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  17. How many bridging oxygen atom are present in P4 O10 ?

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  18. How many moles of H3 PO4 are obtained on hydrolysis of one mole of P4 ...

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  19. On hydrolysis of magnesium nitrate, how many moles of ammonia are prod...

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  20. How many electrons are present in the valence shell of P in PCl3 ?

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