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How many geometrical isomers are there f...

How many geometrical isomers are there fore
(a)`[Co(NH_(3))_(2)CI_(4)]^(Θ)`
(b) `[AuCI_(2)Br_(2)]^(Θ)` (square planar) (c ) `[CuCI_(2)Br_(2)]^(2-)` (tetrahedral) .

Text Solution

Verified by Experts

Since `[Co(NH_(3))_(2)CI_(4)]^(Θ)` is `a [Ma_(2)b_(4)]` type octahedral complex ion it has two geometrical isomers which are cis and trans as shown below

(b) Since `[AuCI_(2)Br_(2)]^(Θ)` ion is `[Ma_(2)b_(2)]` type square planar complex ion it has two geometrical isomers viz cis and trans isomers
(c ) `[CuCI_(2)Br_(2)]^(2-)` is tetrahedral and hence has no geometrical isomer .
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