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An alcohol A, when heated with conc. H(2...

An alcohol A, when heated with conc. `H_(2)SO_(4)` gives an alkene B. When B is bubbled through bromine water and the product obtained is dehydrohalogenated with exccess of sodamide, a new compound C is obtained. The compound C gives D when treated with warm dilute `H_(2)SO_(4)` in the presence of `HgSO_(4)`. D can also be obtained either byh oxidising A with `KMnO_(4)` or form acetic acid through its calcium salt. Identify A, B, C, and D.

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(D) is obtained by distillation of calcium acetante as well as by oxidation of (A) by `KMnO_(4)`. It suggest (D) is acetone and (A) is propan-2-ol.
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An alcohol A, when heated with conc. `H_(2)SO_(4)` gives an alkene B. When B is bubbled through bromine water and the product obtained is dehydrohalogenated with exccess of sodamide, a new compound C is obtained. The compound C gives D when treated with warm dilute `H_(2)SO_(4)` in the presence of `HgSO_(4)`. D can also be obtained either byh oxidising A with `KMnO_(4)` or form acetic acid through its calcium salt. Identify A, B, C, and D.

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एक एल्कोहॉल 'A'`` सान्द्र `H_(2)SO_(4)` के साथ गर्म करने पर एल्कीन `'B'` देता है। `'B'` को ब्रोमीन जल में प्रवाहित करने पर प्राप्त यौगिक का सोदामाइड की अधिकता द्वारा विहाइड्रोजनीकरण करने पर एक नया यौगिक `'C'` बनता है। `'C'HgSO_(4)` की उपस्थित में `H_(2)SO_(4)` से क्रिया कर यौगिक `'D'` देता है । `'A', 'B', 'C'` तथा 'D' यौगिक पहचानिए।

An alcohol (A) on treatment with conc. `H_(2)SO_4` gave an alkene (B). The compound (B), on reacting with `Br_(2)` wate and subsequent dehydrobromination with `NaNH_(2)` produced a compound (C). The compound (C) with dil. `H_(2)SO_(4)` in presence of `HgSO_(4)` gave a compound 'D'. the compound D can also be obtained by oxidation of A by acidified `KMnO_(4)` or from distillation of calcium acetate. calculate molecular weight of 'C'.

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