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The following reaction occurs. Acyl...

The following reaction occurs.

Acylium ion is resonance stabilised.

A

If both `(A)` are `( R)` are true and `( R)` is the correct explanation of `(A)`.

B

If both `(A)` and `( R)` are true but `( R)` is not the correct explanation of `(A)`.

C

If `(A)` is true but `( R)` is false.

D

If `(A)` is false but `( R)` is true.

Text Solution

Verified by Experts

The correct Answer is:
A

Although acid `(I)` is sterically hindered, acylium ion `(A)` is formed as the intermediate which minimises strain. This ion is resonance stabilised due to delocalisation of `pi overline e^, s`.
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  • Assertion : Anilinium chloride is more acidic towards electrophilic substitution than ammonium chloride. reaction. Reason : Anilinium chloride is resonance stabilised

    A
    if both assertion and reason are true and reason is thr correct explanation of assertion
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion
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  • Assertion : Anilinium choride is more acidic than ammonium chloride. Reason : Anilinium ion is resonance-stabilised.

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    if both Assertion and Reason are true and reason is the correct explanation of the assertion.
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    C
    if assertion is true, reason is false
    D
    both assertion and reason are false statements.
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    `CH_(2)=CH-Cl`
    B
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    `CH_(2)=CH-CH_(2)Cl`
    D
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