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The hydrated salt, Na(2)SO(4)*nH(2)O und...

The hydrated salt, `Na_(2)SO_(4)*nH_(2)O` undergoes `55.9%` loss in weight on heating and becomes anhydrous. The value of `n` will be:

A

`5`

B

`3`

C

`7`

D

`10`

Text Solution

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The correct Answer is:
To determine the value of \( n \) in the hydrated salt \( Na_2SO_4 \cdot nH_2O \) that undergoes a 55.9% loss in weight upon heating, we can follow these steps: ### Step 1: Understand the composition of the hydrated salt The hydrated salt is represented as \( Na_2SO_4 \cdot nH_2O \). Here, \( Na_2SO_4 \) is sodium sulfate and \( nH_2O \) represents the water of hydration. ### Step 2: Calculate the molar mass of the components - The molar mass of \( Na_2SO_4 \): - Sodium (Na): \( 22.99 \, g/mol \times 2 = 45.98 \, g/mol \) - Sulfur (S): \( 32.07 \, g/mol \) - Oxygen (O): \( 16.00 \, g/mol \times 4 = 64.00 \, g/mol \) Total for \( Na_2SO_4 \): \[ 45.98 + 32.07 + 64.00 = 142.05 \, g/mol \] - The molar mass of water \( H_2O \): \[ 2 \times 1.01 + 16.00 = 18.02 \, g/mol \] ### Step 3: Write the total molar mass of the hydrated salt The total molar mass of \( Na_2SO_4 \cdot nH_2O \) is: \[ 142.05 + 18.02n \, g/mol \] ### Step 4: Calculate the mass loss upon heating When the hydrated salt is heated, it loses water. The percentage loss in weight is given as 55.9%. This means that the mass of water lost is 55.9% of the total mass of the hydrated salt. If we let \( M \) be the total molar mass of the hydrated salt: \[ M = 142.05 + 18.02n \] The mass of water lost is: \[ \text{Mass of water lost} = 0.559 \times M \] ### Step 5: Set up the equation for the mass of water The mass of water in the hydrated salt is \( 18.02n \). Therefore, we can set up the equation: \[ 18.02n = 0.559 \times (142.05 + 18.02n) \] ### Step 6: Solve for \( n \) Expanding the equation: \[ 18.02n = 0.559 \times 142.05 + 0.559 \times 18.02n \] \[ 18.02n - 0.559 \times 18.02n = 0.559 \times 142.05 \] \[ (18.02 - 0.559 \times 18.02)n = 0.559 \times 142.05 \] \[ (18.02(1 - 0.559))n = 0.559 \times 142.05 \] Calculating \( 1 - 0.559 \): \[ 1 - 0.559 = 0.441 \] Now substituting: \[ (18.02 \times 0.441)n = 0.559 \times 142.05 \] Calculating the left side: \[ 7.94982n = 79.41945 \] Now solving for \( n \): \[ n = \frac{79.41945}{7.94982} \approx 10 \] ### Conclusion The value of \( n \) is approximately 10.

To determine the value of \( n \) in the hydrated salt \( Na_2SO_4 \cdot nH_2O \) that undergoes a 55.9% loss in weight upon heating, we can follow these steps: ### Step 1: Understand the composition of the hydrated salt The hydrated salt is represented as \( Na_2SO_4 \cdot nH_2O \). Here, \( Na_2SO_4 \) is sodium sulfate and \( nH_2O \) represents the water of hydration. ### Step 2: Calculate the molar mass of the components - The molar mass of \( Na_2SO_4 \): - Sodium (Na): \( 22.99 \, g/mol \times 2 = 45.98 \, g/mol \) ...
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Knowledge Check

  • The term mole first used by Ostwald in 1896 refers for the ratio of mass of a substance in g and its molecular weight. 1 "mole" of a gaseous compound occupies 22.4 "litre" at NTP and contains 6.023xx10^(23) molecules of gas. The hydrated salt Na_(2)SO_(4).nH_(2)O undergoes 56% loss in weight on heating and becomes anhydrous. The value of n will be:

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    D
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