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A mixture containing one mole of BaF(2) ...

A mixture containing one mole of `BaF_(2)` and two mole of `H_(2)SO_(4)` will be neutralised by:

A

1 mole `KOH`

B

4 mole `KOH`

C

2 mole `KOH`

D

2 mole `Ca(OH)_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of neutralizing a mixture containing one mole of BaF₂ and two moles of H₂SO₄, we need to follow these steps: ### Step 1: Write the Reaction First, we need to understand the reaction that occurs between BaF₂ and H₂SO₄. Barium fluoride (BaF₂) reacts with sulfuric acid (H₂SO₄) to form barium sulfate (BaSO₄) and hydrofluoric acid (HF): \[ \text{BaF}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{BaSO}_4 + 2\text{HF} \] ### Step 2: Determine the Moles of Products From the balanced equation, we see that one mole of BaF₂ reacts with one mole of H₂SO₄ to produce one mole of BaSO₄ and two moles of HF. Since we have two moles of H₂SO₄, only one mole will react with BaF₂, leaving one mole of H₂SO₄ unreacted. ### Step 3: Identify the Neutralization Requirement To neutralize the remaining unreacted sulfuric acid (H₂SO₄), we need a base. H₂SO₄ is a strong acid that can release two protons (H⁺ ions), so we need two hydroxide ions (OH⁻) to neutralize one mole of H₂SO₄. ### Step 4: Choose the Base The bases that can provide the required hydroxide ions are: - Calcium hydroxide (Ca(OH)₂), which provides two OH⁻ ions per mole. - Potassium hydroxide (KOH), which provides one OH⁻ ion per mole. ### Step 5: Calculate the Required Moles of Base To neutralize one mole of the remaining H₂SO₄: - If we use Ca(OH)₂, we need 1 mole of Ca(OH)₂ (since it provides 2 OH⁻ ions). - If we use KOH, we need 2 moles of KOH (since it provides 1 OH⁻ ion per mole). ### Conclusion Thus, to neutralize the mixture, we can use either: - 1 mole of Ca(OH)₂, or - 2 moles of KOH. ### Final Answer The mixture can be neutralized by either **1 mole of Ca(OH)₂ or 2 moles of KOH**. ---
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Knowledge Check

  • 1 mole of H_(2)SO_(4) will exactly neutralise:

    A
    2 mole of ammonia
    B
    1 mole of `Ba(OH)_(2)`
    C
    0.5 mole of `Ca(OH)_(2)`
    D
    2 mole of KOH
  • 1 mole of H_(2)SO_(4) will exactly neutralise:

    A
    2 mole of ammonia
    B
    1 mole of `Ba(OH)_(2)`
    C
    0.5 moles of `Ca(OH)_(2)`
    D
    2 mole of KOH
  • Mixture of 1 mole BaF_(2) and 2 mole H_(2)SO_(4) can not be neutralised by :

    A
    2 mole `Ba(OH)_(2)`
    B
    2 mole `Ca(OH)_(2)`
    C
    4 mole NaOH
    D
    2 mole KOH
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