Home
Class 11
CHEMISTRY
The relation between change in internal ...

The relation between change in internal energy`(DeltaE)`change in enthalpy`(DeltaH)` and work done`(W)`is represented as

A

`DeltaH=DeltaE+W`

B

`W=DeltaE-DeltaH`

C

`DeltaE=W-DeltaH`

D

`DeltaE=DeltaH+W`

Text Solution

AI Generated Solution

The correct Answer is:
To find the relation between the change in internal energy (ΔE), change in enthalpy (ΔH), and work done (W), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definitions**: - Internal Energy (U): The total energy contained within a system. - Enthalpy (H): A thermodynamic quantity defined as H = U + PV, where P is pressure and V is volume. 2. **Write the Relation for Enthalpy**: - The formula for enthalpy can be expressed as: \[ H = U + PV \] 3. **Differentiate the Enthalpy Expression**: - When we take the change in enthalpy (ΔH), we differentiate the equation: \[ \Delta H = \Delta U + P\Delta V \] 4. **Substitute for Work Done**: - The work done (W) during a process at constant pressure is given by: \[ W = P\Delta V \] - Therefore, we can substitute PΔV in the ΔH equation: \[ \Delta H = \Delta U + W \] 5. **Relate Internal Energy and Change in Internal Energy**: - Since the change in internal energy (ΔE) is often denoted as ΔU, we can write: \[ \Delta H = \Delta E + W \] 6. **Final Relation**: - Thus, the final relation between change in internal energy, change in enthalpy, and work done is: \[ \Delta H = \Delta E + W \] ### Conclusion: The correct relation is: \[ \Delta H = \Delta E + W \]

To find the relation between the change in internal energy (ΔE), change in enthalpy (ΔH), and work done (W), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definitions**: - Internal Energy (U): The total energy contained within a system. - Enthalpy (H): A thermodynamic quantity defined as H = U + PV, where P is pressure and V is volume. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Assertion - Reasoning Questions|7 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise AIPMT/ NEET Questions|53 Videos
  • CHEMICAL EQUILIBRIUM

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

The relationship between enthalpy and internal energy change is

Enthalpy change equal internal energy change when

Knowledge Check

  • The relation between change is internal energy (DeltaE) , change in enthalpy (DeltaH) and work done (W) is represented as

    A
    `DeltaH=DeltaE+W`
    B
    `W=DeltaE-DeltaH`
    C
    `DeltaE=W-DeltaH`
    D
    `DeltaE=DeltaH+W`
  • Enthalpy change equals internal energy change when

    A
    All the reactants and products are in solution.
    B
    reaction is carried out in a closed vessel.
    C
    number of moles of gaseous reactants and that of products is equal.
    D
    reaction is carried out at constant pressure.
  • The relationship between enthalpy change (DeltaH) and internal energy change (DeltaE) for a system is given by

    A
    `DeltaH=DeltaE+PDeltaV`
    B
    `DeltaH=DeltaE-PDeltaV`
    C
    `DeltaH=DeltaE+PV`
    D
    `DeltaH=DeltaE+RT`
  • Similar Questions

    Explore conceptually related problems

    State first law of thermodynamics and state the relation between the change in internal energy (DeltaU) , work done (W) and heat (Q).

    Write the relationship between enthalpy change, DeltaH and internal energy change, DeltaU , for a process occuring at constant pressure and constant temperature.

    Define the terms internal energy change and enthalpy change. How are they related?

    Correct option relation between Delta H (change in enthalpy) and Delta E (change in internal energy) for a gaseous reaction :

    For an ideal gas the relationship between internal energy change Delta U and enthalpy change Delta H is