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The relation between change in internal ...

The relation between change in internal energy`(DeltaE)`change in enthalpy`(DeltaH)` and work done`(W)`is represented as

A

`DeltaH=DeltaE+W`

B

`W=DeltaE-DeltaH`

C

`DeltaE=W-DeltaH`

D

`DeltaE=DeltaH+W`

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The correct Answer is:
To find the relation between the change in internal energy (ΔE), change in enthalpy (ΔH), and work done (W), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definitions**: - Internal Energy (U): The total energy contained within a system. - Enthalpy (H): A thermodynamic quantity defined as H = U + PV, where P is pressure and V is volume. 2. **Write the Relation for Enthalpy**: - The formula for enthalpy can be expressed as: \[ H = U + PV \] 3. **Differentiate the Enthalpy Expression**: - When we take the change in enthalpy (ΔH), we differentiate the equation: \[ \Delta H = \Delta U + P\Delta V \] 4. **Substitute for Work Done**: - The work done (W) during a process at constant pressure is given by: \[ W = P\Delta V \] - Therefore, we can substitute PΔV in the ΔH equation: \[ \Delta H = \Delta U + W \] 5. **Relate Internal Energy and Change in Internal Energy**: - Since the change in internal energy (ΔE) is often denoted as ΔU, we can write: \[ \Delta H = \Delta E + W \] 6. **Final Relation**: - Thus, the final relation between change in internal energy, change in enthalpy, and work done is: \[ \Delta H = \Delta E + W \] ### Conclusion: The correct relation is: \[ \Delta H = \Delta E + W \]

To find the relation between the change in internal energy (ΔE), change in enthalpy (ΔH), and work done (W), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Definitions**: - Internal Energy (U): The total energy contained within a system. - Enthalpy (H): A thermodynamic quantity defined as H = U + PV, where P is pressure and V is volume. ...
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