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The second ionisation enthalpies of elem...

The second ionisation enthalpies of elements are always higher than their first ionisation enthalpies because:

A

cation formed always have stable half-filled or completely filled valence shell electron configuration.

B

It is easier to remove electron process.

C

ionisation is an endothermic process.

D

the cation is smaller than its parent atom.

Text Solution

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The correct Answer is:
D

As elements are ionised, the proton to electron ratio increases, so the attraction between valence shell electron and nucles increases and as a result the size decreases. Therefore, the removal of electorns from smaller cation requires higher energy. Hence the second ionisation enthalpy is greater than its first ionisation enthalpy.
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Knowledge Check

  • The second ionisation enthalpy is

    A
    smaller than the first ionisation enthalpy
    B
    almost equal to the first ionisation enthalpy
    C
    smaller than the third ionisation enthalpy
    D
    equal to the second electron gain enthalpy.
  • The second ionisation energy is always higher than the first ionisation energy because the

    A
    ions become more stable by attaining an octet and duplet configuration
    B
    electron is more tightly bound to the nucleus in an ion
    C
    electron is attracted more by the core electrons
    D
    none of the above
  • The second ionisation enthalpy of an element M is the energy required to

    A
    remove one mole of electrons from one mole of gascous cations of the element
    B
    remove one mole of electrons from onc mole of gaseous anions
    C
    remove one mole of electrons from onc mole of monovalent gascous cations of the element
    D
    remove 2 moles of electrons from one mole of gaseous atoms.
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    Why is the second ionisation energy for a given element always greater than the first ionisation energy?

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    The second ionisation enthalpies of both Cr and Cu are higher than those of the next element. Explain.

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