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Which of the following is the strongest ...

Which of the following is the strongest `-I` group?

A

`-overset(+)(N)(CH_(3))_(3)`

B

`-overset(+)(N)H_(3)`

C

`-overset(+)(S)(CH_(3))_(2)`

D

`-F`

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The correct Answer is:
To determine which of the following is the strongest -I (minus inductive) group, we need to analyze the inductive effects of various substituents. The -I effect refers to the electron-withdrawing ability of a group through sigma bonds due to electronegativity differences. ### Step-by-Step Solution: 1. **Identify the Groups**: First, we need to identify the groups we are comparing. Common -I groups include nitro (-NO2), cyano (-CN), halogens (like -F, -Cl, -Br), and others like -N(CH3)3. 2. **Understand the Inductive Effect**: The -I effect is influenced by the electronegativity of the atoms in the group. The more electronegative the atom, the stronger the -I effect it exerts. 3. **Order of -I Groups**: The typical order of -I groups from strongest to weakest is: - -N(CH3)3 (trimethylammonium) - -NO2 (nitro) - -CN (cyano) - Halogens (-F, -Cl, -Br, -I) - -OH (hydroxyl) can also be considered but is generally not classified as a -I group. 4. **Analyze the Given Groups**: In the context of the question, we are comparing the groups mentioned in the video transcript. The strongest -I group is the one that can withdraw electrons most effectively. 5. **Conclusion**: Based on the analysis, the strongest -I group among the options given is -N(CH3)3 (trimethylammonium). This is because it has a positive charge on nitrogen, which enhances its ability to withdraw electrons through the inductive effect. ### Final Answer: The strongest -I group is **-N(CH3)3**.

To determine which of the following is the strongest -I (minus inductive) group, we need to analyze the inductive effects of various substituents. The -I effect refers to the electron-withdrawing ability of a group through sigma bonds due to electronegativity differences. ### Step-by-Step Solution: 1. **Identify the Groups**: First, we need to identify the groups we are comparing. Common -I groups include nitro (-NO2), cyano (-CN), halogens (like -F, -Cl, -Br), and others like -N(CH3)3. 2. **Understand the Inductive Effect**: The -I effect is influenced by the electronegativity of the atoms in the group. The more electronegative the atom, the stronger the -I effect it exerts. ...
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Section D - Chapter End Test
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