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The correct stability order of the follo...

The correct stability order of the following resonance structure is:
`{:(CH_(2)=C=O,H_(2)overset(-)(C)-overset(+)(C)=O,H_(2)O=overset(+)(C)-overset(-)(O) , H_(2)overset(-)(C)-C-=O),((I),(II),(III),"(IV)"):}`

A

`(IV) gt (I) gt (III)gt(II)`

B

`(II)gt(IV)gt(I)gt(III)`

C

`(III)gt(II)gt(IV)gt(I)`

D

`(I)gt(IV)gt(III)gt(II)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct stability order of the given resonance structures, we will analyze each structure based on their neutrality, octet completion, and the location of charges. ### Step-by-Step Solution: 1. **Identify the Resonance Structures**: - Structure I: \( CH_2=C=O \) - Structure II: \( H_2C^{+}-C^{-}=O \) - Structure III: \( H_2O^{+}-C^{-}=O \) - Structure IV: \( H_2C^{-}-C=O \) 2. **Assess Neutrality**: - Neutral structures are generally more stable than charged ones. - Structure I is neutral, while Structures II, III, and IV have charges. 3. **Evaluate Octet Completion**: - A complete octet contributes to stability. - Structure I has a complete octet for all atoms. - Structure II has an incomplete octet on the positively charged carbon. - Structure III has an incomplete octet on the positively charged carbon. - Structure IV has a complete octet for all atoms. 4. **Analyze Charge Location**: - Negative charges on more electronegative atoms are more stable. - Structure II has a negative charge on carbon, while Structure III has a negative charge on oxygen. - Oxygen is more electronegative than carbon, making Structure III more stable than Structure II. 5. **Ranking the Structures**: - Based on neutrality and octet completion: - Structure I is the most stable (neutral and complete octet). - Structure IV is next (complete octet but has negative charge). - Structure III follows (negative charge on electronegative atom). - Structure II is the least stable (positive charge on carbon and incomplete octet). 6. **Final Stability Order**: - The correct stability order is: - I > IV > III > II ### Conclusion: The correct answer is D: I > IV > III > II.

To determine the correct stability order of the given resonance structures, we will analyze each structure based on their neutrality, octet completion, and the location of charges. ### Step-by-Step Solution: 1. **Identify the Resonance Structures**: - Structure I: \( CH_2=C=O \) - Structure II: \( H_2C^{+}-C^{-}=O \) - Structure III: \( H_2O^{+}-C^{-}=O \) ...
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Give the stability of the following resonance structures (a) H_(2)C = overset(o+)N =overset(Θ) (b) H_(2)overset(o+)C -N =overset(Θ)N (c ) H_(2)overset(Θ)C -overset(o+)N -= N (d) H_(2) overset(Θ)C - N = overset(o+)N .

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Knowledge Check

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    B
    `IgtIIIgtIIgtIV`
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    A
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  • The correct stability order of the following resonance structures is {:((a) H_(2)C = overset(+)N - N^(-) ," "H(2)overset(+)C-N=N^(-)),( (I), " "(II)),(H_(2) overset(-)C-overset(+)N-=N,H_(2)overset(-)C-N=overset(+)N),((III)," "(IV)):}

    A
    `(I) gt (II) gt (IV) gt (III)`
    B
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    C
    `(II) gt (I) gt (III) gt (IV)`
    D
    `(III) gt (I) gt (IV) gt (II)`
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