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Which among the following compounds will...

Which among the following compounds will give maximum enol content in solution?

A

`C_(6)H_(5)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)`

B

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)`

C

`CH_(3)-overset(O)overset(||)(C )-CH_(2)-CH_(2)-CH_(3)`

D

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-COOC_(2)H_(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound will give the maximum enol content in solution, we need to analyze the structures of the compounds provided. Enol content is influenced by the stability of the enol form, which can be affected by factors such as resonance and the presence of electron-withdrawing or electron-donating groups. ### Step-by-Step Solution: 1. **Identify the Compounds**: Let's assume we have four compounds labeled A, B, C, and D. Each compound has different substituents that can influence enol formation. 2. **Analyze Compound A**: - Compound A has a benzene ring attached to a carbonyl group (C=O). - The benzene ring can stabilize the enol form through resonance. The lone pair on the oxygen can participate in resonance with the benzene ring, making the enol form more stable. - This leads to a higher enol content. 3. **Analyze Compound B**: - Compound B has an electron-donating group (like a methyl group) attached to the carbonyl. - Electron-donating groups increase electron density on the carbonyl carbon, making it less favorable for enol formation compared to compound A. - Therefore, the enol content will be lower than that of compound A. 4. **Analyze Compound C**: - Compound C has a carbonyl group with a simple alkyl group. - There is no significant resonance stabilization for the enol form, leading to a lower enol content compared to compounds A and B. 5. **Analyze Compound D**: - Compound D has two carbonyl groups or a more complex structure. - The presence of multiple carbonyls can lead to some stabilization, but if they are involved in resonance, they may not favor enol formation as much as compound A. - Thus, the enol content will be lower than that of compound A. 6. **Conclusion**: - After analyzing all compounds, it is clear that Compound A, with the benzene ring providing resonance stabilization to the enol form, will have the maximum enol content in solution. ### Final Answer: **Compound A will give the maximum enol content in solution.**

To determine which compound will give the maximum enol content in solution, we need to analyze the structures of the compounds provided. Enol content is influenced by the stability of the enol form, which can be affected by factors such as resonance and the presence of electron-withdrawing or electron-donating groups. ### Step-by-Step Solution: 1. **Identify the Compounds**: Let's assume we have four compounds labeled A, B, C, and D. Each compound has different substituents that can influence enol formation. 2. **Analyze Compound A**: ...
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Knowledge Check

  • Which among the following compound will give maximum enol content in solution :

    A
    `C_(6)H_(6)-overset(O)overset(||)C-CH_(2)-overset(O)overset(||)C-CH_(3)`
    B
    `CH_(3)-overset(O)overset(||)C-CH_(2)-overset(O)overset(||)C-CH_(3)`
    C
    `CH_(3)-overset(O)overset(||)C-CH_(2)-CH_(2)-CH_(3)`
    D
    `CH_(3)-overset(O)overset(||)C-CH_(2)-COOC_(2)H_(5)`
  • Maximum enol content is

    A
    B
    C
    D
  • Maximum enol content is in

    A
    B
    C
    D
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