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Which one of the following compounds is ...

Which one of the following compounds is most acidic

A

`Cl-CH_(2)-CH_(2)-OH`

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound is the most acidic among the given options, we can follow these steps: ### Step 1: Understand Acidity Acidity is determined by how easily a compound can donate a proton (H⁺). A more stable conjugate base (the anion formed after losing H⁺) indicates a stronger acid. ### Step 2: Analyze the Compounds We need to analyze the substituents on each compound and how they affect the stability of the conjugate base. ### Step 3: Evaluate Compound A - **Substituent:** Chlorine (Cl) - **Effect:** Chlorine has a -I (inductive) effect, which can stabilize the negative charge somewhat but is not as effective as resonance stabilization. ### Step 4: Evaluate Compound B - **Substituent:** An electron-withdrawing group (e.g., NO₂) - **Effect:** The electron-withdrawing group will stabilize the negative charge on the conjugate base through resonance, making it more stable and thus more acidic. ### Step 5: Evaluate Compound C - **Substituent:** A group that can stabilize the conjugate base through resonance. - **Effect:** The resonance stabilization of the anion will make this compound more acidic than Compound A but less than Compound B. ### Step 6: Evaluate Compound D - **Substituent:** An electron-donating group. - **Effect:** This group will destabilize the conjugate base by increasing electron density, making it less acidic. ### Step 7: Compare Acidity - **Ranking of Acidity:** - Compound B (most acidic due to strong resonance stabilization) - Compound C (next most acidic due to resonance) - Compound A (less acidic due to -I effect) - Compound D (least acidic due to electron-donating effect) ### Conclusion Based on the analysis, **Compound B** is the most acidic because it has the strongest electron-withdrawing group that stabilizes the conjugate base effectively. ### Final Answer **B part is the most acidic.** ---

To determine which compound is the most acidic among the given options, we can follow these steps: ### Step 1: Understand Acidity Acidity is determined by how easily a compound can donate a proton (H⁺). A more stable conjugate base (the anion formed after losing H⁺) indicates a stronger acid. ### Step 2: Analyze the Compounds We need to analyze the substituents on each compound and how they affect the stability of the conjugate base. ...
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Knowledge Check

  • Which of the following compounds is the most acidic ?

    A
    `HCO_(2)H`
    B
    `CH_(3)CO_(2)H`
    C
    `CH_(3)CH_(2)CO_(2)H`
    D
    `"CC"l_(3)CO_(2)H`
  • Which of the following compounds is the most acidic

    A
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    B
    `C_(6)H_(5)CH_(2)`
    C
    `(C_(6)H_(5))CH_(2)`
    D
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  • Which of the following compounds is the most acidic ?

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    B
    C
    D
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