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Which one of the following compounds is ...

Which one of the following compounds is most acidic

A

`Cl-CH_(2)-CH_(2)-OH`

B

C

D

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AI Generated Solution

The correct Answer is:
To determine which compound is the most acidic among the given options, we can follow these steps: ### Step 1: Understand Acidity Acidity is determined by how easily a compound can donate a proton (H⁺). A more stable conjugate base (the anion formed after losing H⁺) indicates a stronger acid. ### Step 2: Analyze the Compounds We need to analyze the substituents on each compound and how they affect the stability of the conjugate base. ### Step 3: Evaluate Compound A - **Substituent:** Chlorine (Cl) - **Effect:** Chlorine has a -I (inductive) effect, which can stabilize the negative charge somewhat but is not as effective as resonance stabilization. ### Step 4: Evaluate Compound B - **Substituent:** An electron-withdrawing group (e.g., NO₂) - **Effect:** The electron-withdrawing group will stabilize the negative charge on the conjugate base through resonance, making it more stable and thus more acidic. ### Step 5: Evaluate Compound C - **Substituent:** A group that can stabilize the conjugate base through resonance. - **Effect:** The resonance stabilization of the anion will make this compound more acidic than Compound A but less than Compound B. ### Step 6: Evaluate Compound D - **Substituent:** An electron-donating group. - **Effect:** This group will destabilize the conjugate base by increasing electron density, making it less acidic. ### Step 7: Compare Acidity - **Ranking of Acidity:** - Compound B (most acidic due to strong resonance stabilization) - Compound C (next most acidic due to resonance) - Compound A (less acidic due to -I effect) - Compound D (least acidic due to electron-donating effect) ### Conclusion Based on the analysis, **Compound B** is the most acidic because it has the strongest electron-withdrawing group that stabilizes the conjugate base effectively. ### Final Answer **B part is the most acidic.** ---

To determine which compound is the most acidic among the given options, we can follow these steps: ### Step 1: Understand Acidity Acidity is determined by how easily a compound can donate a proton (H⁺). A more stable conjugate base (the anion formed after losing H⁺) indicates a stronger acid. ### Step 2: Analyze the Compounds We need to analyze the substituents on each compound and how they affect the stability of the conjugate base. ...
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Section D - Chapter End Test
  1. Find the strongest acid among the following compound

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  2. Among the following the dissociation constant is highest

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  3. Which one of the following compounds is most acidic

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  4. The optically active tartaric acid is named as D-(+)- tartaric acid be...

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  5. Among the following compounds (I-II) the correct order of reaction wit...

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  6. The following reaction is described as

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  7. Which of the following is the most stable cation?

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  8. The observed dipole moment of nitromethane is highly than the dipole m...

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  9. Dehydrohalogenation in presence of OH^(-) is correct represented by

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  10. Among the following the aromatic compound is

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  11. Which of the following compounds are not arranged in order of decreasi...

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  12. Most stable carbonium ion is :

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  13. Which one of the following species is most stable

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  14. Which of the following gives most stable carbocation by dehydration

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  15. Which of the following free radicals would be expected to be most sele...

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  16. The +I effect of alkyl groups is in the order

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  17. How many carbon atoms in the molecule HCOO-(CHOH)(2)-COOH are asymmetr...

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  18. With a change in hybridisation of the carbon bearing the charge, the s...

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  19. The C-C bond length of the following molecules is in the order

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  20. In the reaction CH(3)CHO+HCNtoCH(3)CH(OH)CN a chiral centre is produce...

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