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MnO(4)^(2-) on reduction in acidic mediu...

`MnO_(4)^(2-)` on reduction in acidic medium froms

A

`MnO_(4)`

B

`Mn^(+ +)`

C

`MnO_(4)^(2-)`

D

`Mn`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reduction of \( \text{MnO}_4^{2-} \) in acidic medium, we will follow these steps: ### Step 1: Identify the species involved We start with the manganate ion \( \text{MnO}_4^{2-} \). In acidic medium, we need to consider how this ion behaves during reduction. ### Step 2: Write the half-reaction for the reduction In acidic medium, the manganate ion \( \text{MnO}_4^{2-} \) can be reduced to manganese(II) ion \( \text{Mn}^{2+} \). The half-reaction can be written as follows: \[ \text{MnO}_4^{2-} + 8 \text{H}^+ + 5 \text{e}^- \rightarrow \text{Mn}^{2+} + 4 \text{H}_2\text{O} \] ### Step 3: Balance the half-reaction In this half-reaction, we need to ensure that both mass and charge are balanced. The left side has a charge of \( 2- + 8+ = 6+ \) and the right side has a charge of \( 2+ \). The addition of 5 electrons on the left side balances the charge. ### Step 4: Conclusion Thus, when \( \text{MnO}_4^{2-} \) is reduced in acidic medium, it forms \( \text{Mn}^{2+} \). ### Final Answer The final product of the reduction of \( \text{MnO}_4^{2-} \) in acidic medium is \( \text{Mn}^{2+} \). ---
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Determine the equivalent weight of the following oxidising and reducing agents : (a) KMnO_(4) (reacting in acidic medium MnO_(4)^(-)rarrMn^(2+) ) (b) KMnO_(4) (reacting in neutral medium MnO_(4)^(-)rarr MnO_(2) )

The number of moles of oxalate ions oxidised by one mole of MnO_(4)^(-) ion in acidic medium is :

Knowledge Check

  • MnO_(4)^(-) on reduction in acid medium forms-

    A
    `MnO_(2)`
    B
    `MnO_(4)^(-)`
    C
    `Mn`
    D
    `Mn^(+ +)`
  • Assertion: (A): The reactions between NH_(3) and MnO_(4)^(ө) occurs in an acidic medium. NH_(3)+MnO_(4)^(ө)rarrMnO_(2)+NO_(2) Reason (R ): MnO_(4)^(ө) is reduced to MnO_(2) in acidic medium.

    A
    If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.
    B
    If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.
    C
    If `(A)` is correct but `(R )` is incorrect.
    D
    If both `(A)` and `(R )` are incorrect.
  • The equivalent weight of MnO_(4)^(-) ion in acidic medium is

    A
    `31.6`
    B
    `23.8`
    C
    55
    D
    119
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