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The co-ordination number of cobalt in th...

The co-ordination number of cobalt in the complex `[Co(en)_2Br_2]Cl_2` is

A

(a) `2`

B

(b) `6`

C

(c) `5`

D

(d) `4`

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The correct Answer is:
To determine the coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\), we will analyze the ligands attached to the cobalt ion. ### Step-by-Step Solution: 1. **Identify the central metal atom**: The central metal atom in the complex is cobalt (Co). 2. **Identify the ligands**: The ligands in the complex are: - \(en\) (ethylenediamine), which is a bidentate ligand. - \(Br\) (bromide), which is a monodentate ligand. 3. **Determine the contribution of each ligand to the coordination number**: - Each \(en\) ligand can bind to the cobalt through two donor atoms (nitrogen atoms). Since there are 2 \(en\) ligands, they contribute: \[ 2 \, \text{(from one } en\text{)} \times 2 \, \text{(number of } en\text{ ligands)} = 4 \] - Each \(Br\) ligand can bind through one donor atom. Since there are 2 \(Br\) ligands, they contribute: \[ 1 \, \text{(from one } Br\text{)} \times 2 \, \text{(number of } Br\text{ ligands)} = 2 \] 4. **Calculate the total coordination number**: Now, we add the contributions from both types of ligands: \[ \text{Total coordination number} = 4 \, \text{(from } en\text{)} + 2 \, \text{(from } Br\text{)} = 6 \] 5. **Conclusion**: The coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\) is 6. ### Final Answer: The coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\) is **6**.

To determine the coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\), we will analyze the ligands attached to the cobalt ion. ### Step-by-Step Solution: 1. **Identify the central metal atom**: The central metal atom in the complex is cobalt (Co). 2. **Identify the ligands**: ...
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A2Z-COORDINATION COMPOUNDS-Section D - Chapter End Test
  1. The co-ordination number of cobalt in the complex [Co(en)2Br2]Cl2 is

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  2. Co-ordination number of Fe in the complexes [Fe(CN)6]^(4-), [Fe(CN)6]^...

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  3. (Me)(2) SiCl(2) on hydrolysis will produce.

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  4. Types of isomerism shown by [Cr(NH3)5NO2]Cl2 is

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  5. Which of the following will no give a precipate with AgNO3?

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  6. In the process of extraction of gold, Roasted gold ore +CN^(-)+H2Oov...

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  7. A reagent used for identifying nickel ion is:

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  8. Which of the following complex is an outer orbital complex?

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  9. Which of the following has the largest number of isomers? .

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  10. Which kind of isomerism is exhibited by octahedral [Co(NH(3))(4)Br(2)]...

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  11. Which one of the following is expected to exhibit optical isomerism (e...

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  12. The pair of the compounds in which both the metals are in the highest ...

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  13. IUPAC name of [Co(NH3)5NO2]Cl2

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  14. Which of the following is considered to be an anticancer species ?

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  15. An aqueous solution of COCL2 on addition of excess of concentrated HCl...

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  16. The correct order for the wavelength of absorption in the visible regi...

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  17. In which of the following pairs both the complex show optical isomeris...

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  18. Which of the following compounds shows optical isomerism?

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  19. CN^(-) is a strong field ligand. This is due to the fact that

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  20. Considering H2O as a weak field ligand, the number of unpaired electro...

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  21. Given the molecular formula of the hexacoordinated complexes (A) [CoCl...

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