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The co-ordination number of cobalt in th...

The co-ordination number of cobalt in the complex `[Co(en)_2Br_2]Cl_2` is

A

(a) `2`

B

(b) `6`

C

(c) `5`

D

(d) `4`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\), we will analyze the ligands attached to the cobalt ion. ### Step-by-Step Solution: 1. **Identify the central metal atom**: The central metal atom in the complex is cobalt (Co). 2. **Identify the ligands**: The ligands in the complex are: - \(en\) (ethylenediamine), which is a bidentate ligand. - \(Br\) (bromide), which is a monodentate ligand. 3. **Determine the contribution of each ligand to the coordination number**: - Each \(en\) ligand can bind to the cobalt through two donor atoms (nitrogen atoms). Since there are 2 \(en\) ligands, they contribute: \[ 2 \, \text{(from one } en\text{)} \times 2 \, \text{(number of } en\text{ ligands)} = 4 \] - Each \(Br\) ligand can bind through one donor atom. Since there are 2 \(Br\) ligands, they contribute: \[ 1 \, \text{(from one } Br\text{)} \times 2 \, \text{(number of } Br\text{ ligands)} = 2 \] 4. **Calculate the total coordination number**: Now, we add the contributions from both types of ligands: \[ \text{Total coordination number} = 4 \, \text{(from } en\text{)} + 2 \, \text{(from } Br\text{)} = 6 \] 5. **Conclusion**: The coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\) is 6. ### Final Answer: The coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\) is **6**.

To determine the coordination number of cobalt in the complex \([Co(en)_2Br_2]Cl_2\), we will analyze the ligands attached to the cobalt ion. ### Step-by-Step Solution: 1. **Identify the central metal atom**: The central metal atom in the complex is cobalt (Co). 2. **Identify the ligands**: ...
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Knowledge Check

  • Statement-1:Coordination number of cobalt in the complex [Co(en)_(3)]^(3+) is six. Statement-2: Ethylenediamine acts as a bidentate ligand.

    A
    Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-1.
    B
    Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.
    C
    Statement-1 is True, Statement-2 is False.
    D
    Statement-1 is False, Statement-2 is True.
  • Statement-1:Coordination number of cobalt in the complex [Co(en)_(3)]^(3+) is six. Statement-2: Ethylenediamine acts as a bidentate ligand.

    A
    Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for Statement-1.
    B
    Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.
    C
    Statement-1 is True, Statement-2 is False.
    D
    Statement-1 is False, Statement-2 is True.
  • The oxidation number , d-orbital occupation and co-ordination number of cr in the complex Cis- [Cr(en)_(2)Cl_(2)]Cl are respectively .

    A
    `+3, 3d` and 4
    B
    `+3,4d` and 6
    C
    `+3, 3d` and 6
    D
    `+2, 3d` and 6
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