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The coordination number of Pt in [Pt(NH3...

The coordination number of Pt in `[Pt(NH_3)_4Cl_2]` ion is

A

(a) `2`

B

(b) `4`

C

(c) `6`

D

(d) `8`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the coordination number of platinum (Pt) in the complex ion \([Pt(NH_3)_4Cl_2]\), we follow these steps: ### Step 1: Identify the Central Metal Atom The central metal atom in the given complex is platinum (Pt). ### Step 2: Identify the Ligands The ligands attached to the platinum in this complex are: - 4 ammonia molecules (\(NH_3\)) - 2 chloride ions (\(Cl^-\)) ### Step 3: Determine the Type of Ligands - Ammonia (\(NH_3\)) is a monodentate ligand, meaning it can attach to the metal at one point. - Chloride ions (\(Cl^-\)) are also monodentate ligands. ### Step 4: Count the Number of Ligands Now, we count the total number of ligand atoms attached to the platinum: - From 4 ammonia molecules, we have 4 nitrogen atoms contributing to the coordination. - From 2 chloride ions, we have 2 chlorine atoms contributing to the coordination. ### Step 5: Calculate the Coordination Number The coordination number is the total number of ligand atoms attached to the central metal atom. Therefore, we add the contributions from both types of ligands: - Coordination number from \(NH_3\): 4 - Coordination number from \(Cl^-\): 2 Total coordination number = \(4 + 2 = 6\) ### Conclusion Thus, the coordination number of platinum in \([Pt(NH_3)_4Cl_2]\) is **6**. ---
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Knowledge Check

  • [Pt(NH_3)_4]CL_2 is

    A
    pyramidal
    B
    pentagonal
    C
    tetrahedral
    D
    square planar
  • The oxidation and coordination number of Pt in [Pt(C_(2)H_(4))Cl_(3)]^(-) is respectively :-

    A
    `+1,3`
    B
    `+2,4`
    C
    `+3,6`
    D
    `+2,5`
  • The oxidation number of Pt in [Pt(C_2H_4)Cl_3]^- is

    A
    `+1`
    B
    `+2`
    C
    `+3`
    D
    `+4`
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