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CH(2)= CHCH(2)CH=CH(2) overset(NBS)rarr ...

` CH_(2)= CHCH_(2)CH=CH_(2) overset(NBS)rarr X(` Major `),(X)` is `:`

A

B

`CH_(20=CH-CH=CH-CH_(2)-Br`

C

`CH_(2)=CHCH_(2)CH=CHBr`

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of the compound \( CH_2=CHCH_2CH=CH_2 \) with NBS (N-bromosuccinimide), we will follow these steps: ### Step 1: Identify the Reactant The reactant is \( CH_2=CHCH_2CH=CH_2 \), which is a conjugated diene. ### Step 2: Understand the Role of NBS NBS is used for bromination at the allylic position. The allylic position refers to the carbon atoms adjacent to the carbon-carbon double bond. ### Step 3: Identify the Allylic Positions In the given diene, the allylic positions are: - The carbon atoms adjacent to the double bonds. - For the first double bond \( CH_2=CH \), the allylic carbon is \( CH_2 \) (the carbon connected to the double bond). - For the second double bond \( CH=CH_2 \), the allylic carbon is \( CH_2 \) (the carbon connected to the double bond). ### Step 4: Mechanism of Reaction The bromination occurs via a free radical mechanism: 1. NBS generates bromine radicals. 2. The bromine radical can attack the allylic carbon, leading to the formation of a radical at that position. ### Step 5: Determine the Major Product 1. If bromination occurs at the first allylic position (the first \( CH_2 \)): - The product formed will be \( CH_2=CHCHBrCH=CH_2 \). 2. If bromination occurs at the second allylic position (the second \( CH_2 \)): - The product formed will be \( CH_2=CHCH=CHBrCH_2 \). ### Step 6: Resonance Stabilization - The radical formed by bromination at the second allylic position is more stable due to resonance. - The resonance structures allow for delocalization of the radical, making it more stable than the radical formed at the first allylic position. ### Step 7: Conclusion The major product formed from the reaction of \( CH_2=CHCH_2CH=CH_2 \) with NBS is: \[ CH_2=CHCH=CHCH_2Br \] ### Final Answer Thus, the major product \( X \) is \( CH_2=CHCH=CHCH_2Br \). ---

To solve the question regarding the reaction of the compound \( CH_2=CHCH_2CH=CH_2 \) with NBS (N-bromosuccinimide), we will follow these steps: ### Step 1: Identify the Reactant The reactant is \( CH_2=CHCH_2CH=CH_2 \), which is a conjugated diene. ### Step 2: Understand the Role of NBS NBS is used for bromination at the allylic position. The allylic position refers to the carbon atoms adjacent to the carbon-carbon double bond. ...
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Knowledge Check

  • CH_2=CHCH_2=CH_2overset(NBS)rarrA A is

    A
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    B
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    B
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  • CH_(2)=CH-CH_(2)-CH-CH_(2)overset(NBS)to[A]. The major product [A] is

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    C
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